The synergetic effect of two Si− H groups leads to efficient reduction of carboxamides to
amines by platinum catalysts under mild conditions. The rate of the reaction is dependent on …

Vinylsilanes are versatile synthetic building blocks, which in recent years have played an
increasing role in the synthesis of complex molecules. This article provides an overview of …

The first highly efficient ligand-controlled regio-and stereodivergent intermolecular
hydrosilylations of internal alkynes have been disclosed. Cationic ruthenium complexes …

The defined Fe hydride complex FeH (CO)(NO)(Ph3P) 2 is highly active as a catalyst for
selective hydrosilylation of internal alkynes to vinylsilanes. Depending on the silane …

Rule of thumb: The high yielding title reaction is described with a focus on understanding the
factors that govern the regioselectivity of the process (see scheme). Electronic, steric, and …

Evidence of the involvement of a “cocktail”-type catalytic system in the alkyne and alkene
hydrosilylation reaction in the presence of platinum on a carbon support is reported. The …

The combined use of a catalytic amount of silver acetate and a stoichiometric amount of
DBU efficiently catalyzed the incorporation of CO2 under mild reaction conditions into a wide …

HCl in solution accepts electron density from Au NPs and partially reduces at room
temperature, as occurs with other simple diatomic molecules, such as O2 and H2. The …

New impregnated platinum on magnetite catalyst has been prepared, characterized and
used for the hydrosilylation of different alkynes. The catalyst showed a wide reaction scope …

Regioselective hydration of a wide range of internal alkynes has been afforded in high to
good yields by using PTSA in EtOH. The scope of the reaction of alkynes has been …