Cryogenic and temperature-dependent photoelectron spectroscopy of metal complexes

Q Yuan, W Cao, XB Wang - International Reviews in Physical …, 2020 - Taylor & Francis
Negative ion photoelectron spectroscopy (NIPES) coupled with electrospray ionisation (ESI)
has been proven to be a powerful gas-phase spectroscopic tool for characterising electronic …

Coordination complexes of transition metals (M= Mo, Fe, Rh, and Ru) with Tin (II) phthalocyanine in neutral, monoanionic, and dianionic states

DV Konarev, AV Kuzmin, Y Nakano… - Inorganic …, 2016 - ACS Publications
The ability of tin atoms to form stable Sn–M bonds with transition metals was used to prepare
transition metal complexes with tin (II) phthalocyanine in neutral, monoanionic, and …

CO activation by the heterobinuclear transition metal-iron clusters: A photoelectron spectroscopic and theoretical study

J Zhang, Z Liu, G Li, H Fan, L Jiang, H Xie - Journal of Energy Chemistry, 2021 - Elsevier
Spectroscopic characterization of CO activation on multiple metal-containing catalysts
remains an important and challenging goal for identifying the structure and nature of active …

Probing the bonding of CO to heteronuclear group 4 metal–nickel clusters by photoelectron spectroscopy

J Zou, H Xie, Q Yuan, J Zhang, D Dai, H Fan… - Physical Chemistry …, 2017 - pubs.rsc.org
A series of heterobinuclear group 4 metal–nickel carbonyls MNi (CO) n−(M= Ti, Zr, Hf; n= 3–
7) has been generated via a laser vaporization supersonic cluster source and characterized …

Distonic radical anion species in cysteine oxidation processes

Z Qin, GL Hou, Z Yang, M Valiev… - Physical Chemistry …, 2020 - pubs.rsc.org
Oxidation of cysteine residues constitutes an important regulatory mechanism in the function
of biological systems. Much of this behavior is controlled by the specific chemical properties …

Photoelectron velocity-map imaging and theoretical studies of heteronuclear metal carbonyls MNi (CO) 3−(M= Mg, Ca, Al)

H Xie, J Zou, Q Yuan, H Fan, Z Tang… - The Journal of Chemical …, 2016 - pubs.aip.org
The heteronuclear metal carbonyl anions MNi (CO) 3−(M= Mg, Ca, Al) have been
investigated using photoelectron velocity-map imaging spectroscopy. Electron affinities of …

Disproportionation of Bis(phosphaethenyl)pyridine Iron(I) Bromide Induced by tBuNC

YF Lin, N Ichihara, Y Nakajima, F Ozawa - Organometallics, 2014 - ACS Publications
Redox behavior of Fe (I) complexes bearing a PNP-pincer-type phosphaalkene ligand, 2, 6-
bis [1-phenyl-2-(2, 4, 6-tri-tert-butylphenyl)-2-phosphaethenyl] pyridine (BPEP-Ph), is …

Nature of the M–M bonding (M= Cr, Mo, and W) in [CpM (CO) 3] 2: Covalent single bond or noncovalent interaction?

X Zhang, D Meng, X Li, L Meng, Z Sun - Journal of Organometallic …, 2014 - Elsevier
The nature of metal–metal bonding in [CpM (CO) 3] 2 (M= Cr, Mo, W; Cp= C 5 H 5) was
characterized within the framework of the atoms in molecules theory, electron localization …

Negative Ion Photoelectron Spectroscopy Reveals Remarkable Noninnocence of Ligands in Nickel Bis(dithiolene) Complexes [Ni(dddt)2] and [Ni(edo)2]

X Liu, GL Hou, X Wang, XB Wang - The Journal of Physical …, 2016 - ACS Publications
[Ni (dddt) 2]−(dddt= 5, 6-dihydro-1, 4-dithiine-2, 3-dithiolate) and [Ni (edo) 2]−(edo= 5, 6-
dihydro-1, 4-dioxine-2, 3-dithiolate) are two donor-type nickel bis (dithiolene) complexes …

Adiabatic Electron Detachment Energies, Reaction Barriers, Chemical Balance, and Ligand Effects on the Nucleophilicities of Metal Carbonyl Monoanions

H Wang, Y Wang, H Li, Y Hu, Q Fan, RB King… - …, 2022 - ACS Publications
The absolute values of the adiabatic electron detachment energies (ADBEs) of transition
metal carbonyl monoanions are equivalent to the adiabatic electron affinities of the …