Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and …

S Daliran, AR Oveisi, Y Peng… - Chemical Society …, 2022 - pubs.rsc.org
Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

Linker Engineering for Reactive Oxygen Species Generation Efficiency in Ultra-Stable Nickel-Based Metal–Organic Frameworks

K Wu, XY Liu, PW Cheng, YL Huang… - Journal of the …, 2023 - ACS Publications
Interfacial charge transfer on the surface of heterogeneous photocatalysts dictates the
efficiency of reactive oxygen species (ROS) generation and therefore the efficiency of …

Locking effect in metal@ MOF with superior stability for highly chemoselective catalysis

Y Zhong, P Liao, J Kang, Q Liu, S Wang… - Journal of the …, 2023 - ACS Publications
Ultrasmall metal nanoparticles (NPs) show high catalytic activity in heterogeneous catalysis
but are prone to reunion and loss during the catalytic process, resulting in low …

Functional metal–organic frameworks as effective sensors of gases and volatile compounds

HY Li, SN Zhao, SQ Zang, J Li - Chemical Society Reviews, 2020 - pubs.rsc.org
Developing efficient sensor materials with superior performance for selective, fast and
sensitive detection of gases and volatile organic compounds (VOCs) is essential for human …

Introducing Brønsted acid sites to accelerate the bridging-oxygen-assisted deprotonation in acidic water oxidation

Y Wen, C Liu, R Huang, H Zhang, X Li… - Nature …, 2022 - nature.com
Oxygen evolution reaction (OER) consists of four sequential proton-coupled electron transfer
steps, which suffer from sluggish kinetics even on state-of-the-art ruthenium dioxide (RuO2) …

Catalysis by metal organic frameworks: perspective and suggestions for future research

D Yang, BC Gates - Acs Catalysis, 2019 - ACS Publications
Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering
high densities of catalytic sites in high-area porous solids, some with stabilities at high …

The chemistry and applications of hafnium and cerium (IV) metal–organic frameworks

Z Hu, Y Wang, D Zhao - Chemical Society Reviews, 2021 - pubs.rsc.org
The coordination connection of organic linkers to the metal clusters leads to the formation of
metal–organic frameworks (MOFs), where the metal clusters and ligands are spatially …

Confining atomically precise nanoclusters in metal–organic frameworks for advanced catalysis

YM Li, J Hu, M Zhu - Coordination Chemistry Reviews, 2023 - Elsevier
Combining metal nanoclusters (NCs) with functional supports provides excellent potential
for exploring the host–guest interactions and rational design of highly active NC-based …

Recent advances in the development of electronically and ionically conductive metal-organic frameworks

G Zhang, L Jin, R Zhang, Y Bai, R Zhu… - Coordination Chemistry …, 2021 - Elsevier
As porous materials, metal–organic frameworks (MOFs) have drawn increased attention and
are widely applied in various fields such as catalysis, gas/energy storage, chemical sensing …