Light to shape the future: from photolithography to 4D printing

J del Barrio… - Advanced Optical Materials, 2019 - Wiley Online Library
Over the last few decades, the demand of polymeric structures with well‐defined features of
different size, dimension, and functionality has increased from various application areas …

Recent advances in alkyne-based click polymerizations

D Huang, Y Liu, A Qin, BZ Tang - Polymer Chemistry, 2018 - pubs.rsc.org
Click chemistry, with remarkable advantages such as high efficiency, atom economy, mild
reaction conditions, very high yield, regio-and/or stereoselectivity, and good functionality …

Catalytic activation of bioorthogonal chemistry with light (CABL) enables rapid, spatiotemporally controlled labeling and no-wash, subcellular 3D-patterning in live …

A Jemas, Y Xie, JE Pigga, JL Caplan… - Journal of the …, 2022 - ACS Publications
Described is the spatiotemporally controlled labeling and patterning of biomolecules in live
cells through the catalytic activation of bioorthogonal chemistry with light, referred to as …

Enabling In Vivo Photocatalytic Activation of Rapid Bioorthogonal Chemistry by Repurposing Silicon-Rhodamine Fluorophores as Cytocompatible Far-Red …

C Wang, H Zhang, T Zhang, X Zou… - Journal of the …, 2021 - ACS Publications
Chromophores that absorb in the tissue-penetrant far-red/near-infrared window have long
served as photocatalysts to generate singlet oxygen for photodynamic therapy. However, the …

Ligand-directed photocatalysts and far-red light enable catalytic bioorthogonal uncaging inside live cells

JE Rosenberger, Y Xie, Y Fang, X Lyu… - Journal of the …, 2023 - ACS Publications
Described are ligand-directed catalysts for live-cell, photocatalytic activation of
bioorthogonal chemistry. Catalytic groups are localized via a tethered ligand either to DNA …

Click-Chemistry-Enabled Functionalization of Cellulose Nanocrystals with Single-Stranded DNA for Directed Assembly

D Bukharina, K Cauffiel, LM Killingsworth… - ACS Biomaterials …, 2024 - ACS Publications
Controlling the self-assembly of cellulose nanocrystals (CNCs) requires precise control over
their surface chemistry for the directed assembly of advanced nanocomposites with tailored …

Towards understanding the kinetic behaviour and limitations in photo-induced copper (i) catalyzed azide–alkyne cycloaddition (CuAAC) reactions

BM El-Zaatari, AU Shete, BJ Adzima… - Physical Chemistry …, 2016 - pubs.rsc.org
The kinetic behaviour of the photo-induced copper (I) catalyzed azide–alkyne cycloaddition
(CuAAC) reaction was studied in detail using real-time Fourier transform infrared (FTIR) …

Phosphonium tetraphenylborate: a photocatalyst for visible-light-induced, nucleophile-initiated thiol-michael addition photopolymerization

X Zhang, X Wang, S Chatani, CN Bowman - ACS Macro Letters, 2020 - ACS Publications
A photoinitiation system that utilizes phosphonium tetraphenylborate as the key component
was developed for the visible light-triggered nucleophile-catalyzed thiol-Michael addition …

Bismesitoylphosphinic Acid (BAPO‐OH): A Ligand for Copper Complexes and Four‐Electron Photoreductant for the Preparation of Copper Nanomaterials

A Beil, G Müller, D Käser, B Hattendorf… - Angewandte Chemie …, 2018 - Wiley Online Library
Abstract Bismesitoylphosphinic acid,(HO) PO (COMes) 2 (BAPO‐OH), is an efficient
photoinitiator for free‐radical polymerizations of olefins in aqueous phase. Described here …

CuAAC–methacrylate interpenetrating polymer network (IPN) properties modulated by visible-light photoinitiation

M Kabra, CJ Kloxin - Polymer Chemistry, 2023 - pubs.rsc.org
Interpenetrating polymer networks (IPNs) are a class of materials with interwoven polymers
that exhibit unique blended or enhanced properties useful in a variety of applications …