This review is the first to collate and summarize main data on named and unnamed
rearrangement reactions of peroxides. It should be noted, that in the chemistry of peroxides …

Covering: 1998 up to the end of 2023 Since its initial disclosure in 1951, the Kornblum
DeLaMare rearrangement has proved an important synthetic transformation and has been …

We have investigated the continuous flow photooxidation of several conjugated dienes and
subsequent rearrangement using a practical and safe continuous-flow homemade …

We report the enantioselective total syntheses of zeylenol (+)‐1, as well as its congeners (−)‐
7 and 16, and of 3‐O‐debenzoylzeylenone 28. To this end, a new variant of the Kornblum …

Despite the availability of alternative methods for drying tetrahydrofuran (THF), the use of the
still apparatus, wherein a THF solution containing Na-bezophenone ketyl is heated to reflux …

Advanced intermediates for the syntheses of tetrodotoxin reported by the groups of
Fukuyama, Alonso, and Sato were prepared. Key steps include the toluene dioxygenase …

Two new deoxycarbaheptopyranoses, 5a-carba-6-deoxy-α-dl-galacto-heptopyranose and
5a-carba-6-deoxy-α-dl-gulo-heptopyranose were prepared starting from cyclohexa-1, 4 …

Both enantiomers of 8-oxabicyclo [3.2. 1] oct-3-en-2-one (6) have been synthesized from 4-
hydroxycyclohept-2-enone (3) on the basis of a novel oxidative cyclo-etherification using PhI …

The first total synthesis of polyhydroxylated cyclohexenone 1, isolated from Pleiogynium
timorense and named pleiogenone A, is reported that also serves as a proof of structure and …

For the synthesis of bromo-conduritol-B skeleton, bromo-1, 4-benzoquinone was subjected
to bromination followed by the reduction of the carbonyl groups with NaBH4. Substitution of …