1, 1, 1, 3, 3, 3-Hexafluoroisopropanol (HFIP) is a polar, strongly hydrogen bond-donating
solvent that has found numerous uses in organic synthesis due to its ability to stabilize ionic …

Electrochemistry has recently gained increased attention as a versatile strategy for
achieving challenging transformations at the forefront of synthetic organic chemistry …

Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …

Aziridines—three-membered nitrogen-containing cyclic molecules—are important synthetic
targets. Their substantial ring strain and resultant proclivity towards ring-opening reactions …

Electrochemical fluorination (ECF) refers to the introduction of fluorine-containing moieties
into organic molecules under electrochemical conditions. The primary objective of this …

This review summarizes the progress in the fluorination and fluoroalkylation of electron‐rich
systems with diverse fluorine (F) and fluoroalkyl (Rfn) reagents employing hypervalent …

The clinical success of α, α-difluorocyclopropanes, combined with limitations in the existing
synthesis portfolio, inspired the development of an operationally simple, organocatalysis …

Electrochemistry has a lot of inherent advantages in organic synthesis and many redox
reactions have been achieved under electrochemical condition. However, the …

Short aliphatic groups are prevalent in bioactive small molecules and play an essential role
in regulating physicochemistry and molecular recognition phenomena. Delineating their …

Conspectus Hypervalent iodine reagents find application as selective chemical oxidants in a
diverse array of oxidative transformations. The utility of these reagents is often ascribed to …