Electrostatic interactions within mixed-valent compounds

A Hildebrandt, D Miesel, H Lang - Coordination Chemistry Reviews, 2018 - Elsevier
The electrochemical properties of bi-and multi-metallic compounds are a convolution of
several factors, among which through-bond electron transfer and through-space electrostatic …

Electronic coupling in 1, 2, 3-triazole bridged ferrocenes and its impact on reactive oxygen species generation and deleterious activity in cancer cells

P Biegański, E Kovalski, N Israel, E Dmitrieva… - Inorganic …, 2022 - ACS Publications
Mixed-valence (MV) binuclear ferrocenyl compounds have long been studied as models for
testing theories of electron transfer and in attempts to design molecular-scale electronic …

Triple the fun: tris (ferrocenyl) arene-based gold (I) complexes for redox-switchable catalysis

A Straube, P Coburger, L Dütsch, E Hey-Hawkins - Chemical Science, 2020 - pubs.rsc.org
The modular syntheses of C3-symmetric tris (ferrocenyl) arene-based tris-phosphanes and
their homotrinuclear gold (I) complexes are reported. Choosing the arene core allows fine …

Rearrangements and Migrations along the Ferrocene Periphery: On the Way to Planar‐Chiral and (Multi) Substitution Patterns

M Korb, H Lang - European Journal of Inorganic Chemistry, 2022 - Wiley Online Library
The functionalization of ferrocenes via intramolecular rearrangements is summarized. Focus
will be directed on anionic, cationic and thermal/photo‐induced processes that enable the …

Transition-Metal Carbonyl Complexes of 2,5-Diferrocenyl-1-phenyl-1H-phosphole

D Miesel, A Hildebrandt, M Korb… - …, 2015 - ACS Publications
Pentacarbonyl (2, 5-diferrocenyl-1-phenyl-1 H-phosphole) metal complexes 3a–c (3a, M=
Cr; 3b, M= Mo; 3c, M= W) have successfully been synthesized by the reaction of 2, 5 …

Ferrocenyl‐Pyrenes, Ferrocenyl‐9, 10‐Phenanthrenediones, and Ferrocenyl‐9, 10‐Dimethoxyphenanthrenes: Charge‐Transfer Studies and SWCNT …

A Preuß, S Notz, E Kovalski, M Korb… - … A European Journal, 2020 - Wiley Online Library
Abstract The synthesis of 1‐Fc‐(3), 1‐Br‐6‐Fc‐(5 a), 2‐Br‐7‐Fc‐(7 a), 1, 6‐Fc2‐(5 b), 2, 7‐
Fc2‐pyrene (7 b), 3, 6‐Fc2‐9, 10‐phenanthrenedione (10), and 3, 6‐Fc2‐9, 10 …

Benzodithiophene and Benzotrithiophene as π Cores for Two‐and Three‐Blade Propeller‐Shaped Ferrocenyl‐Based Conjugated Systems

S Rossi, A Bisello, R Cardena, L Orian… - European Journal of …, 2017 - Wiley Online Library
The syntheses of linear and star‐shaped bis‐and tris (ferrocenyl) derivatives of benzo [1, 2‐
b: 4, 5‐b′] dithiophene and benzo [1, 2‐b: 3, 4‐b′: 5, 6‐b′′] trithiophene are achieved …

Ferrocenyl naphthalenes: substituent-and substitution pattern-depending charge transfer studies

A Preuß, M Korb, D Miesel, T Rüffer… - Dalton …, 2019 - pubs.rsc.org
The synthesis of a series of ferrocenyl-functionalized naphthalenes of type 2-Fc-C10H7 (3a),
1-Fc-2-R-C10H6 (3b, R= OMe; 3c, R= Me; 3d, R= H; 3e, R= CH (O)), 1, 1′-(C10H7) …

Ferrocenyl GNA Nucleosides: A Bridge between Organic and Organometallic Xeno‐nucleic Acids

J Skiba, Q Yuan, A Hildebrandt, H Lang… - …, 2018 - Wiley Online Library
The enantioselective synthesis and electrochemistry of the first ferrocenyl GNA nucleosides
is reported. These compounds were obtained by a Sharpless asymmetric dihydroxylation …

Testing the conjugative properties of benzodithiophene and benzotrithiophene in charge transfer multi (ferrocenyl) systems

S Rossi, A Bisello, R Cardena, S Santi - Organometallics, 2018 - ACS Publications
The charge transfer properties of the mono-, di-, and tricationic derivatives of bis (ferrocenyl)
benzodithiophene and tris (ferrocenyl) benzotrithiophene were investigated. The cations …