For an atom with such a uniquely simple electronic makeup, hydrogen shows remarkable
mutability as a ligand. As a one-electron substituent with no significant potential for π-type …

Abstract Complexes of Group 2, 12, 13, 14, 15 and 16 elements with mono-, bi-, and poly-
dentate phosphine and arsine ligands (and including the very few examples of stibine and …

Tertiary amine adducts of alane show a diverse range of structures based on four and five
coordinate species, hydride bridging dimeric and polymeric species, and ionic species …

A primary factor influencing catalyticversus stoichiometric behaviour of molecular main
group species in homogeneous dehydrocoupling reactions is the redox stability of the metal …

The dimers of [H3N⊙ BH3] 2,[H3N⊙ AlH3] 2, and [H3N⊙ GaH3] 2 are characterized as
head-to-tail complexes with intermolecular H− H hydrogen bonding. In the case of [H3N⊙ …

The new compounds [H2GaE (SiMe3) 2] 3 (E= P (1), As (2)), the first authenticated examples
of a phosphinogallane and an arsinogallane containing the GaH2 moiety, are prepared via …

A recent review* 1 has described the currentstate of knowledge of base-free, unsaturated
hydride derivatives of Al—Tl as a “wasteland” comparedto that of boron hydrides. A small …

Thin-film deposition and microelectronic device fabrication have been the driving forces for
the recent resurgence of synthetic1· 2 and theoretical3 interest in the donor adducts of …

Thermally stable mono-tri-t-butylphosphine adducts of alane and gallane, H 3 Mp t Bu 3 (M
Al, 1; M Ga, 2) and the gallane rich adducts of 1, 2-bis (diisopropylphosphino) ethane and …

7Dipp Complexes of the group 13 binary hydrides GaH3 and InH3 have been prepared.
Both adducts possess excellent thermal stability in the solid state but decompose readily in …