Cyanation: a photochemical approach and applications in organic synthesis
Photoredox chemistry has emerged as an efficient tool in catalyzing organic reactions as it
utilizes light as an energy source without any external initiator or reagent. The cyanide group …
utilizes light as an energy source without any external initiator or reagent. The cyanide group …
Nickel-catalyzed cyanation of aryl halides and hydrocyanation of alkynes via C–CN bond cleavage and cyano transfer
H Chen, S Sun, YA Liu, X Liao - ACS Catalysis, 2019 - ACS Publications
We report nickel-catalyzed cyanation and hydrocyanation methods to prepare aryl nitriles
and vinyl nitriles from aryl halides and alkynes, respectively. Using inexpensive and …
and vinyl nitriles from aryl halides and alkynes, respectively. Using inexpensive and …
Flavin nitroalkane oxidase mimics compatibility with NOx/TEMPO catalysis: aerobic oxidization of alcohols, diols, and ethers
Biomimetic flavin organocatalysts oxidize nitromethane to formaldehyde and NO x—
providing a relatively nontoxic, noncaustic, and inexpensive source for catalytic NO2 for …
providing a relatively nontoxic, noncaustic, and inexpensive source for catalytic NO2 for …
New fluorescent heterocyclic compounds derived from 3-Cyanobenzanthrone
A Maļeckis, L Avotiņa, G Ķizāne, A Pučkins… - Polycyclic Aromatic …, 2022 - Taylor & Francis
The four-cyclic condensed aromatic ketone 7 H-benz [de] anthracene-7-one and its
derivatives belong to the class of important anthraquinoid dyes, including laser and …
derivatives belong to the class of important anthraquinoid dyes, including laser and …
Synthesis and characterization of a green and recyclable arginine-based palladium/CoFe 2 O 4 nanomagnetic catalyst for efficient cyanation of aryl halides
S HajimohamadzadehTorkambour, MJ Nejad… - RSC …, 2024 - pubs.rsc.org
The utilization of magnetic nanoparticles in the fields of science and technology has gained
considerable popularity. Among their various applications, magnetic nanoparticles have …
considerable popularity. Among their various applications, magnetic nanoparticles have …
Fluorinated Vilsmeier Reagent: TFEDMA‐mediated Synthesis of Aryl‐cyanides and Aryl‐amides via the Activation of Oximes
AK Yadav, S Reddy Narra… - Asian Journal of …, 2023 - Wiley Online Library
A convenient method for the activation of aryl‐oximes is reported using 1, 1, 2, 2‐tetrafluoro‐
N, N‐dimethylethylamine (TFEDMA) as a scalable and efficient reagent. Aryl‐aldoximes led …
N, N‐dimethylethylamine (TFEDMA) as a scalable and efficient reagent. Aryl‐aldoximes led …
Organic transformations in nitromethane as solvent
B Banerjee, M Kaur, A Singh, A Sharma… - … Products Isolation, Drug …, 2023 - degruyter.com
Nitromethane is the simplest nitro-compound. At normal conditions, it is liquid in nature. It is
used as a reagent, solvent, stabilizer and fuel in sports car and rockets [1]. It is a highly polar …
used as a reagent, solvent, stabilizer and fuel in sports car and rockets [1]. It is a highly polar …
Methods for Direct Conversion of Primary Nitroalkanes to Nitriles
M Ganesan - Current Organic Chemistry, 2021 - ingentaconnect.com
In recent years, reductive dehydration of primary nitro compounds has been demonstrated
as an attractive and alternative approach for the direct synthesis of nitriles. Although …
as an attractive and alternative approach for the direct synthesis of nitriles. Although …
Synthesis of aryloxyacetonitriles based on arylboronic acids with 2-bromoacetonitrile
Y Li, M Guo, Y Wen, L Zhou, X Shen, Y Kang - Tetrahedron Letters, 2020 - Elsevier
A new and efficient protocol for the synthesis of aryloxyacetonitriles based on arylboronic
acids with 2-bromoacetonitrile has been developed using eco-friendly hydrogen peroxide as …
acids with 2-bromoacetonitrile has been developed using eco-friendly hydrogen peroxide as …
Carbanions and Electrophilic Aliphatic Substitution
ML Birsa - Organic Reaction Mechanisms· 2016: An annual …, 2020 - Wiley Online Library
Summary This Chapter Contains Sections titled: Carbanion Structure and Stability
Carbanion Reactions Enolates and Related Species Heteroatom‐Stabilized Species …
Carbanion Reactions Enolates and Related Species Heteroatom‐Stabilized Species …