Amine–Boranes as transfer hydrogenation and hydrogenation reagents: A mechanistic perspective
S Lau, D Gasperini, RL Webster - … Chemie International Edition, 2021 - Wiley Online Library
Transfer hydrogenation (TH) has historically been dominated by Meerwein–Ponndorf–
Verley (MPV) reactions. However, with growing interest in amine–boranes, not least …
Verley (MPV) reactions. However, with growing interest in amine–boranes, not least …
[HTML][HTML] Ammonia borane-enabled hydrogen transfer processes: Insights into catalytic strategies and mechanisms
Transfer hydrogenation (TH) with in situ generated hydrogen donor is of great importance in
reduction reactions, and an alternative strategy to traditional hydrogenation processes …
reduction reactions, and an alternative strategy to traditional hydrogenation processes …
Controlling N-doping type in carbon to boost single-atom site Cu catalyzed transfer hydrogenation of quinoline
Single-atom site (SA) catalysts on N-doped carbon (CN) materials exhibit prominent
performance for their active sites being MN x. Due to the commonly random doping …
performance for their active sites being MN x. Due to the commonly random doping …
Surface-enhanced Raman scattering active gold nanoparticles with enzyme-mimicking activities for measuring glucose and lactate in living tissues
Gold nanoparticles (AuNPs) with simultaneous plasmonic and biocatalytic properties
provide a promising approach to developing versatile bioassays. However, the combination …
provide a promising approach to developing versatile bioassays. However, the combination …
One-step synthesis of core-gold/shell-ceria nanomaterial and its catalysis for highly selective semihydrogenation of alkynes
T Mitsudome, M Yamamoto, Z Maeno… - Journal of the …, 2015 - ACS Publications
We report a facile synthesis of new core-Au/shell-CeO2 nanoparticles (Au@ CeO2) using a
redox-coprecipitation method, where the Au nanoparticles and the nanoporous shell of …
redox-coprecipitation method, where the Au nanoparticles and the nanoporous shell of …
Accelerating chemo-and regioselective hydrogenation of alkynes over bimetallic nanoparticles in a metal–organic framework
Selective semihydrogenation of alkynes has been a long-term and significant target, yet it
remains a great challenge. Herein, bimetallic nanoparticles in a metal–organic framework …
remains a great challenge. Herein, bimetallic nanoparticles in a metal–organic framework …
Silica-supported Cu nanoparticle catalysts for alkyne semihydrogenation: effect of ligands on rates and selectivity
Narrowly dispersed, silica-supported Cu nanoparticles (ca. 2 nm) prepared via surface
organometallic chemistry from a mesityl complex [Cu5Mes5] are highly active for the …
organometallic chemistry from a mesityl complex [Cu5Mes5] are highly active for the …
Design of core-Pd/shell-Ag nanocomposite catalyst for selective semihydrogenation of alkynes
T Mitsudome, T Urayama, K Yamazaki, Y Maehara… - ACS …, 2016 - ACS Publications
We designed core-Pd/shell-Ag nanocomposite catalyst (Pd@ Ag) for highly selective
semihydrogenation of alkynes. The construction of the core–shell nanocomposite enables a …
semihydrogenation of alkynes. The construction of the core–shell nanocomposite enables a …
Unveiling the synthetic potential of substituted phenols as fully recyclable organophotoredox catalysts for the iodosulfonylation of olefins
We describe an efficient photocatalytic procedure for the direct iodosulfonylation of terminal
olefins 3 with α-iodo phenylsulfones 4. Specifically, the process uses the simple, robust, and …
olefins 3 with α-iodo phenylsulfones 4. Specifically, the process uses the simple, robust, and …
Stereoselective Transfer Semi‐Hydrogenation of Alkynes to E‐Olefins with N‐Heterocyclic Silylene–Manganese Catalysts
YP Zhou, Z Mo, MP Luecke… - Chemistry–A European …, 2018 - Wiley Online Library
The synthesis and structures of the first SiII‐donor supported manganese (II) complexes [L1]
MnCl2,[L2] MnCl2, and [L3] 2MnCl2 are reported, bearing a pincer‐type bis (NHSi)‐pyridine …
MnCl2,[L2] MnCl2, and [L3] 2MnCl2 are reported, bearing a pincer‐type bis (NHSi)‐pyridine …