Unconventional singlet fission materials
Singlet fission (SF) is a photophysical downconversion pathway, in which a singlet excitation
transforms into two triplet excited states. As such, it constitutes an exciton multiplication …
transforms into two triplet excited states. As such, it constitutes an exciton multiplication …
Cibalackrot‐type compounds: Stable singlet fission materials with aromatic ground state and excited state
W Zeng, DW Szczepanik… - Journal of Physical …, 2023 - Wiley Online Library
Singlet fission is a multiexciton generation process, where one singlet exciton is absorbed
and two triplet excitons are produced. The potential of more efficient photovoltaic devices …
and two triplet excitons are produced. The potential of more efficient photovoltaic devices …
Strategies for design of potential singlet fission chromophores utilizing a combination of ground-state and excited-state aromaticity rules
O El Bakouri, JR Smith, H Ottosson - Journal of the American …, 2020 - ACS Publications
Singlet exciton fission photovoltaic technology requires chromophores with their lowest
excited states arranged so that 2 E (T1)< E (S1) and E (S1)< E (T2). Herein, qualitative …
excited states arranged so that 2 E (T1)< E (S1) and E (S1)< E (T2). Herein, qualitative …
Singlet fission in a pyrrole-fused cross-conjugated skeleton with adaptive aromaticity
L Wang, L Lin, J Yang, Y Wu, H Wang… - Journal of the …, 2020 - ACS Publications
Singlet fission (SF) materials hold the potential to increase the power conversion efficiency
of solar cells by reducing the thermalization of high-energy excited states. The major hurdle …
of solar cells by reducing the thermalization of high-energy excited states. The major hurdle …
Energy component analysis for electronically excited states of molecules: why the lowest excited state is not always the HOMO/LUMO transition
P Kimber, F Plasser - Journal of Chemical Theory and …, 2023 - ACS Publications
The ability to tune excited-state energies is crucial to many areas of molecular design. In
many cases, this is done based on the energies of the highest occupied molecular orbital …
many cases, this is done based on the energies of the highest occupied molecular orbital …
Triplet Formation in a 9, 10-Bis (phenylethynyl) anthracene Dimer and Trimer Occurs by Charge Recombination Rather than Singlet Fission
R Ringström, ZW Schroeder… - The Journal of …, 2023 - ACS Publications
We present an experimental study investigating the solvent-dependent dynamics of a 9, 10-
bis (phenylethynyl) anthracene monomer, dimer, and trimer. Using transient absorption …
bis (phenylethynyl) anthracene monomer, dimer, and trimer. Using transient absorption …
Excited state character of Cibalackrot-type compounds interpreted in terms of Hückel-aromaticity: a rationale for singlet fission chromophore design
The exact energies of the lowest singlet and triplet excited states in organic chromophores
are crucial to their performance in optoelectronic devices. The possibility of utilizing singlet …
are crucial to their performance in optoelectronic devices. The possibility of utilizing singlet …
Inverse design of tetracene polymorphs with enhanced singlet fission performance by property-based genetic algorithm optimization
The efficiency of solar cells may be improved by using singlet fission (SF), in which one
singlet exciton splits into two triplet excitons. SF occurs in molecular crystals. A molecule …
singlet exciton splits into two triplet excitons. SF occurs in molecular crystals. A molecule …
Singlet fission rate: Optimized packing of a molecular pair. Ethylene as a model
A Zaykov, P Felkel, EA Buchanan… - Journal of the …, 2019 - ACS Publications
A procedure is described for unbiased identification of all π-electron chromophore pair
geometry choices that locally maximize the rate of conversion of a singlet exciton into a …
geometry choices that locally maximize the rate of conversion of a singlet exciton into a …
High-performance solution-processed red hyperfluorescent OLEDs based on cibalackrot
Hyperfluorescent organic light-emitting diodes (OLEDs) have allowed remarkable device
performances to be achieved using fluorescent emitters. Superior device performance has …
performances to be achieved using fluorescent emitters. Superior device performance has …