Mass spectrometry of polymers: A tutorial review

C Wesdemiotis, KN Williams‐Pavlantos… - Mass Spectrometry …, 2024 - Wiley Online Library
Ever since the inception of synthetic polymeric materials in the late 19th century, the number
of studies on polymers as well as the complexity of their structures have only increased. The …

Telechelic poly (2-oxazoline) s

G Delaittre - European Polymer Journal, 2019 - Elsevier
While they were first reported as early as 1966, poly (2-oxazoline) s (PAOx) have made a
strong resurgence in the last 20 years, mostly due to their high promises in the field of …

The Kendrick analysis for polymer mass spectrometry

TNJ Fouquet - Journal of Mass Spectrometry, 2019 - Wiley Online Library
The mass spectrum of a polymer often displays repetitive patterns with peak series spaced
by the repeating unit (s) of the polymeric backbones, sometimes complexified with different …

Rapid visualization of chemically related compounds using Kendrick mass defect as a filter in mass spectrometry imaging

C Kune, A McCann, LR Raphaël, AA Arias… - Analytical …, 2019 - ACS Publications
Kendrick mass defect (KMD) analysis is widely used for helping the detection and
identification of chemically related compounds based on exact mass measurements. We …

Characterization across a dispersity: polymer mass spectrometry in the second dimension

TE Morgan, CA Wootton, B Marzullo… - Journal of the …, 2021 - ACS Publications
Due to the natural dispersity that is present in synthetic polymers, an added complexity is
always present in the analysis of polymeric species. Tandem mass spectrometry analysis …

Graphical ranking of divisors to get the most out of a resolution-enhanced Kendrick mass defect plot

S Nakamura, RB Cody, H Sato, T Fouquet - Analytical chemistry, 2018 - ACS Publications
Resolution-enhanced Kendrick Mass Defect (KMD) analysis using the new concept of
fractional base units (repeating unit R divided by integer X; R/X as a mathematical moiety) is …

An arsenal of tools based on Kendrick mass defects to process congested electrospray ionization high‐resolution mass spectra of polymers with multiple charging

K Ishitsuka, T Kakiuchi, H Sato… - … in Mass Spectrometry, 2020 - Wiley Online Library
Rationale Electrospray ionization (ESI) favors the multiple charging of high molecular weight
polymer samples and allows their high‐resolution mass analysis in the low‐mass range. It …

Tandem mass spectrometry for polymeric structure analysis: A comparison of two common MALDI–ToF/ToF techniques

JS Town, GR Jones, E Hancox… - Macromolecular …, 2019 - Wiley Online Library
Tandem mass spectrometry is a powerful technique for investigating polymer architecture.
However, in‐depth studies of the technique for polymers is relatively lacking when …

Stochasticity of poly (2-oxazoline) oligomer hydrolysis determined by tandem mass spectrometry

TE Morgan, TG Floyd, BP Marzullo, CA Wootton… - Polymer …, 2022 - pubs.rsc.org
Understanding modification of synthetic polymer structures is necessary for their accurate
synthesis and potential applications. In this contribution, a series of partially hydrolyzed poly …

Electron Capture Dissociation of Trithiocarbonate-Terminated Acrylamide Homo-and Copolymers: A Terminus-Directed Mechanism?

TE Morgan, A Kerr, CA Wootton, MP Barrow… - Analytical …, 2020 - ACS Publications
The structure and sequence elucidation of complex homo-and copolymers is key for further
understanding polymers, polymer synthesis, and polymer interactions in biological …