Synthesis, spectroscopic, crystallographic, quantum and molecular docking investigations of cis-4, 5-diphenylimidazolidine-2-thione

AS Faihan, RH AlShammari, M Ashfaq… - Journal of Molecular …, 2023 - Elsevier
We present the synthesis and characterization of stereoselective thione. The synthetic
procedure includes readily available starting materials and minimum side products. The …

Synthesis, characterization, and x-ray crystallography of unexpected chloro-substitution on 1-(4-chlorophenyl)-3-phenylthiourea platinum (II) complex with tertiary …

AS Faihan, NM Aziz, M Ashfaq, WMI Hassan… - Journal of Molecular …, 2022 - Elsevier
Abstract The reaction of 1-(4-chlorophenyl)-3-phenylthiourea (CPTH 2) with [PtCl 2 (PPh 3)
2] moiety in a 1: 1 molar ratio in a basic solution afforded unexpected Pt (II) thiourea dianion …

Promising bio-active complexes of platinum (II) and palladium (II) derived from heterocyclic thiourea: Synthesis, characterization, DFT, molecular docking, and anti …

AS Faihan, MR Hatshan, MM Kadhim… - Journal of Molecular …, 2022 - Elsevier
Abstract Four Platinum (II) and Palladium (II) heterocyclic thiourea complexes have been
prepared;[Pt (CPPT) 2](1),[Pd (CPPT) 2](2),[Pt (MPPT) 2](3), and [Pd (MPPT) 2](4)(Where …

Cd (II) and Pd (II) mixed ligand complexes of dithiocarbamate and tertiary phosphine ligands—Spectroscopic, anti-microbial, and computational studies

TB Abdullah, R Behjatmanesh-Ardakani, AS Faihan… - Molecules, 2023 - mdpi.com
Mixed ligand complexes of Pd (II) and Cd (II) with N-picolyl-amine dithiocarbamate (PAC-
dtc) as primary ligand and tertiary phosphine ligand as secondary ligands have been …

Spectroscopic, biological activity studies, and DFT calculations, of Pd (II) and Pt (II) complexes of 4-Methylene-3-phenyl-3, 4-dihydroquinazoline-2 (1H)-thione

AMA Al-Janabi, AS Faihan, AM Al-Mutairi… - Journal of the Indian …, 2022 - Elsevier
Four palladium (II) and platinum (II) complexes with the formula [MCl 2 (HPhqS) 2] and [M
(PhqS) 2](M II= Pd and Pt), were synthesized by treating Na 2 PdCl 4 or K 2 PtCl 4 with 2 mol …

Mixed ligand complexes of Pt (II) Tertiary phosphines and 1-(benzo [d] thiazol-2-yl)-3-phenylthiourea; Crystal structure and DFT of [Pt (C14H9N3S2)(dppe)]. CH2Cl2

AA Alwagdani, AS Faihan, M Ashfaq… - Journal of Molecular …, 2025 - Elsevier
This paper describes a series of Pt (II) thiourea complexes (1–4). The complexes were
synthesized by a reaction between [PtCl 2 (diphos)] and the ligand 1-(benzo [d] thiazol-2-yl) …

Spectroscopic, Anti-Cancer Activity, and DFT Computational Studies of Pt (II) Complexes with 1-Benzyl-3-phenylthiourea and Phosphine/Diamine Ligands

DS Mohamed, SA Al-Jibori, R Behjatmanesh-Ardakani… - Inorganics, 2023 - mdpi.com
The reaction between [PtCl2 (LL)](LL= dppe, dppp, dppb, dppf, Phen and Bipy) or [PtCl2
(PPh3) 2] with 1-benzyl-3-phenylthiourea (H2BPT) in a basic medium (CHCl3/EtOH) created …

Synthesis, characterization and biological activity studies of Pd (II) and Pt (II)–2H-benzo [e][1, 3] oxazine-2, 4 (3H)-dione (HBzoxe) complexes

WH Khalaf, SA Al-Jibori, M Ashfaq, AS Faihan… - Chemical Papers, 2024 - Springer
Mixed-ligand complexes of Pd (II) and Pt (II) with 2H-benzo [e][1, 3] oxazine-2, 4 (3H)-dione
(HBzoxe), tertiary phosphines (dppe, dppp, dppf and Ph3P), 2, 2′-bipyridine (Bipy) and 1 …

A Slightly Distorted Square Pyramidal Nickel (II) Complex: Synthesis, Characterizations, X-ray Crystal Structure, Anticancer Activity, Electrochemistry, DFT and …

RA Saleh, HA Mohamad, M Ashfaq, SA Al-Jibori… - Chemistry Africa, 2024 - Springer
Abstract Treatment of NiCl2. 6H2O with two equivalents of 1, 2-bis (diphenylphosphino)
ethane (dppe) in MeOH/CH2Cl2 afforded [NiCl (dppe) 2] Cl. CH2Cl2 in 89% yield. The …

Thiourea Derivative Metal Complexes: Spectroscopic, Anti-Microbial Evaluation, ADMET, Toxicity, and Molecular Docking Studies

ATF Al-Halbosy, AA Hamada, AS Faihan, AM Saleh… - Inorganics, 2023 - mdpi.com
The treatment of N-Phenylmorpholine-4-carbothioamide (HPMCT) with bivalent metal ions
in a 2: 1 mol ratio without a base present affords [MCl2 (κ 1S-HPMCT) 2]{M= Cu (1), Pd (2) …