Electrical conductivity and magnetic bistability in metal–organic frameworks and coordination polymers: charge transport and spin crossover at the nanoscale

V Rubio-Giménez, S Tatay… - Chemical Society …, 2020 - pubs.rsc.org
Materials scientists are currently shifting from purely inorganic, organic and silicon-based
materials towards hybrid organic–inorganic materials to develop increasingly complex and …

Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks

ZP Ni, JL Liu, MN Hoque, W Liu, JY Li, YC Chen… - Coordination Chemistry …, 2017 - Elsevier
The incorporation of spin-crossover (SCO) properties into metal-organic frameworks (MOFs)
is an appealing subclass of multifunctional MOFs with potential applications in molecular …

Nanoscale crystalline architectures of Hofmann-type metal–organic frameworks

K Otsubo, T Haraguchi, H Kitagawa - Coordination Chemistry Reviews, 2017 - Elsevier
Metal–organic frameworks (MOFs) have been of particular interest to researchers because
of their structural designability, robustness, and rich science arising from uniform porosity …

Symmetry breaking in iron (II) spin-crossover molecular crystals

N Ortega-Villar, MC Muñoz, JA Real - Magnetochemistry, 2016 - mdpi.com
This review provides an up to date survey of a singular class of iron (II) spin crossover (SCO)
molecular materials that undergo high-spin (HS)↔ low-spin (LS) phase transitions …

Thermo-and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer

T Delgado, M Meneses-Sánchez, L Piñeiro-López… - Chemical …, 2018 - pubs.rsc.org
The search for bifunctional materials showing synergies between spin crossover (SCO) and
luminescence has attracted substantial interest since they could be promising platforms for …

Structure–property relationships and the mechanisms of multistep transitions in spin crossover materials and frameworks

J Cruddas, BJ Powell - Inorganic Chemistry Frontiers, 2020 - pubs.rsc.org
Spin crossover frameworks and molecular crystals display fascinating collective behaviours.
This includes multi-step transitions with hysteresis and a wide variety of long-range ordered …

Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au)

VM Hiiuk, SI Shylin, DD Barakhtii, DM Korytko… - Inorganic …, 2022 - ACS Publications
Two 2D Hofmann-type complexes of the composition [Fe (Phpz) 2 {M (CN) 2} 2](where
Phpz= 2-phenylpyrazine; M= Ag, Au) have been synthesized, and their spin-crossover …

Spin crossover in FeII cyanometallic frameworks

OI Kucheriv, IO Fritsky, A Il'ya - Inorganica Chimica Acta, 2021 - Elsevier
Spin-crossover (SCO) compounds represent a huge class of switchable coordination
complexes that can change their electronic configurations under the influence of different …

Spin crossover in Fe (II)–M (II) cyanoheterobimetallic frameworks (M= Ni, Pd, Pt) with 2-substituted pyrazines

OI Kucheriv, SI Shylin, V Ksenofontov… - Inorganic …, 2016 - ACS Publications
Discovery of spin-crossover (SCO) behavior in the family of FeII-based Hofmann clathrates
has led to a “new rush” in the field of bistable molecular materials. To date this class of SCO …

Extrinsic vs. intrinsic luminescence and their interplay with spin crossover in 3D Hofmann-type coordination polymers

M Meneses-Sánchez, L Piñeiro-López… - Journal of Materials …, 2020 - pubs.rsc.org
The research of new multifunctional materials, as those undergoing spin crossover (SCO)
and luminescent properties, is extremely important in the development of further optical and …