Recent Advances in the Direct Synthesis of H2O2
RJ Lewis, GJ Hutchings - ChemCatChem, 2019 - Wiley Online Library
Abstract Hydrogen peroxide (H2O2) is a highly effective, green oxidant that has found
application in sectors ranging from the synthesis of fine chemicals and waste stream …
application in sectors ranging from the synthesis of fine chemicals and waste stream …
Characterisation of gold catalysts
A Villa, N Dimitratos, CE Chan-Thaw… - Chemical Society …, 2016 - pubs.rsc.org
Au-based catalysts have established a new important field of catalysis, revealing specific
properties in terms of both high activity and selectivity for many reactions. However, the …
properties in terms of both high activity and selectivity for many reactions. However, the …
Effect of Pd Coordination and Isolation on the Catalytic Reduction of O2 to H2O2 over PdAu Bimetallic Nanoparticles
The direct synthesis of hydrogen peroxide (H2+ O2→ H2O2) may enable low-cost H2O2
production and reduce environmental impacts of chemical oxidations. Here, we synthesize a …
production and reduce environmental impacts of chemical oxidations. Here, we synthesize a …
Enhanced Selective Oxidation of Benzyl Alcohol via In Situ H2O2 Production over Supported Pd-Based Catalysts
Bimetallic Pd-Fe catalysts supported on TiO2 are shown to be highly effective toward the
selective oxidation of benzyl alcohol to benzaldehyde via the in situ production of H2O2 from …
selective oxidation of benzyl alcohol to benzaldehyde via the in situ production of H2O2 from …
A residue-free approach to water disinfection using catalytic in situ generation of reactive oxygen species
T Richards, JH Harrhy, RJ Lewis, AGR Howe… - Nature Catalysis, 2021 - nature.com
Globally, water disinfection is reliant on chlorination, but requires a route that avoids the
formation of chemical residues. Hydrogen peroxide, a broad-spectrum biocide, can offer …
formation of chemical residues. Hydrogen peroxide, a broad-spectrum biocide, can offer …
The roles of metal co-catalysts and reaction media in photocatalytic hydrogen production: Performance evaluation of M/TiO2 photocatalysts (M= Pd, Pt, Au) in different …
M/TiO 2 photocatalyst activity for H 2 production depends on both the metal co-catalyst (M)
and the reaction medium. To quantify such effects, we compared the performance of M/TiO 2 …
and the reaction medium. To quantify such effects, we compared the performance of M/TiO 2 …
Zirconium‐oxo Nodes of MOFs with Tunable Electronic Properties Provide Effective⋅ OH Species for Enhanced Methane Hydroxylation
G Fang, JN Hu, LC Tian, JX Liang, J Lin… - Angewandte Chemie …, 2022 - Wiley Online Library
Direct conversion of methane to high value‐added oxygenates under mild conditions has
attracted extensive interest. However, the over‐oxidation of target products is usually …
attracted extensive interest. However, the over‐oxidation of target products is usually …
Direct Synthesis of H2O2 from H2 and O2 on Pd Catalysts: Current Understanding, Outstanding Questions, and Research Needs
DW Flaherty - ACS catalysis, 2018 - ACS Publications
Catalytic reactions that utilize H2O2 as a terminal oxidant possess high selectivities for
industrially relevant oxidations that rival Cl2 mediated chemistry and reactions with organic …
industrially relevant oxidations that rival Cl2 mediated chemistry and reactions with organic …
Tandem catalysis for selective oxidation of methane to oxygenates using oxygen over PdCu/zeolite
B Wu, T Lin, M Huang, S Li, J Li, X Yu… - Angewandte Chemie …, 2022 - Wiley Online Library
Selective oxidation of methane to oxygenates with O2 under mild conditions remains a great
challenge. Here we report a ZSM‐5 (Z‐5) supported PdCu bimetallic catalyst (PdCu/Z‐5) for …
challenge. Here we report a ZSM‐5 (Z‐5) supported PdCu bimetallic catalyst (PdCu/Z‐5) for …
Active sites and mechanisms for H2O2 decomposition over Pd catalysts
A Plauck, EE Stangland, JA Dumesic… - Proceedings of the …, 2016 - National Acad Sciences
A combination of periodic, self-consistent density functional theory (DFT-GGA-PW91)
calculations, reaction kinetics experiments on a SiO2-supported Pd catalyst, and mean-field …
calculations, reaction kinetics experiments on a SiO2-supported Pd catalyst, and mean-field …