Divergent gold catalysis: unlocking molecular diversity through catalyst control

CC Chintawar, AK Yadav, A Kumar… - Chemical …, 2021 - ACS Publications
The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds

VW Bhoyare, AG Tathe, A Das, CC Chintawar… - Chemical Society …, 2021 - pubs.rsc.org
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Gold-catalyzed synthesis of small rings

M Mato, A Franchino, C Garcı́a-Morales… - Chemical …, 2020 - ACS Publications
Three-and four-membered rings, widespread motifs in nature and medicinal chemistry, have
fascinated chemists ever since their discovery. However, due to energetic considerations …

Silver-catalysed reactions of alkynes: recent advances

G Fang, X Bi - Chemical Society Reviews, 2015 - pubs.rsc.org
Silver is a less expensive noble metal. Superior alkynophilicity due to π-coordination with
the carbon–carbon triple bond makes silver salts ideal catalysts for alkyne-based organic …

Synthesis of heterocycles via palladium-catalyzed carbonylations

XF Wu, H Neumann, M Beller - Chemical Reviews, 2013 - ACS Publications
Palladium-catalyzed coupling reactions have become a powerful tool in organic synthesis. 1
Today, there are numerous applications of palladium catalysts in the preparation of …

Transition metal-mediated synthesis of monocyclic aromatic heterocycles

AV Gulevich, AS Dudnik, N Chernyak… - Chemical …, 2013 - ACS Publications
Transition Metal-Mediated Synthesis of Monocyclic Aromatic Heterocycles | Chemical Reviews
ACS ACS Publications C&EN CAS Find my institution Log In Chemical Reviews ACS …

Gold-catalyzed cyclopropanation reactions using a carbenoid precursor toolbox

D Qian, J Zhang - Chemical Society Reviews, 2015 - pubs.rsc.org
Homogeneous gold-catalyzed cyclopropanation has emerged as a powerful method in
organic synthesis due to its rich chemistry and fascinating reactivity. This thriving strategy is …

Gold-catalyzed nucleophilic cyclization of functionalized allenes: a powerful access to carbo-and heterocycles

N Krause, C Winter - Chemical reviews, 2011 - ACS Publications
Allenes are highly valuable synthetic precursors in preparative organic chemistry because of
their ability to undergo a variety of transformations. 1 Among many different reaction modes …

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

H Clavier, SP Nolan - Chemical Communications, 2010 - pubs.rsc.org
Electronic and steric ligand effects both play major roles in organometallic chemistry and
consequently in metal-mediated catalysis. Quantifying such parameters is of interest to …

Stable cyclic carbenes and related species beyond diaminocarbenes

M Melaimi, M Soleilhavoup… - Angewandte Chemie …, 2010 - Wiley Online Library
The success of homogeneous catalysis can be attributed largely to the development of a
diverse range of ligand frameworks that have been used to tune the behavior of various …