Solvothermal synthesis of Group 13–15 chalcogenidometalates with chelating organic amines

J Zhou, J Dai, GQ Bian, CY Li - Coordination chemistry reviews, 2009 - Elsevier
Inorganic–organic hybrid chalcogenidometalate materials have attracted considerable
interest, because they are a new type of materials with unique topologic structures. The …

Synthesis of inorganic-organic hybrid thiometallate materials with a special focus on thioantimonates and thiostannates and in situ X-Ray Scattering Studies of their …

B Seidlhofer, N Pienack, W Bensch - Zeitschrift für Naturforschung B, 2010 - degruyter.com
A rich variety of inorganic-organic hybrid thioantimonates and thiostannates were prepared
during the last few years under solvothermal conditions applying organic amine molecules …

Organically directed heterometallic chalcogenidometalates containing group 12 (II)/13 (III)/14 (IV) metal ions and antimony (III)

KY Wang, ML Feng, XY Huang, J Li - Coordination Chemistry Reviews, 2016 - Elsevier
Crystalline chalcogenidometalates are a class of solid-state materials with great significance
for both basic science and technological applications. The strong dependence of their …

Assembly of novel organic-decorated quaternary TM–Hg–Sb–Q compounds (TM= Mn, Fe, Co; Q= S, Se) by the combination of three types of metal coordination …

KY Wang, LJ Zhou, ML Feng, XY Huang - Dalton Transactions, 2012 - pubs.rsc.org
Four organic-decorated quaternary TM–Hg–Sb–Q compounds, namely,[Mn (phen)]
2HgSb2S6 (phen= 1, 10-phenanthroline)(1) and isomorphic [TM (tren)] HgSb2Se5 (TM= Mn …

Synthesis, crystal structure, electronic structure, and photoelectric response properties of KCu 2 SbS 3

R Wang, X Zhang, J He, C Zheng, J Lin… - Dalton Transactions, 2016 - pubs.rsc.org
Copper thioantimonates have received enormous attention due to their potential for
applications in photovoltaic devices. In this work, a new layered compound KCu2SbS3 was …

Solvothermal Syntheses, Crystal Structures and Selected Optical Properties of [M(C8N5H23)]2Sn2S6 (M = Co, Fe, Ni; C8N5H23 …

N Pienack, S Lehmann, H Lühmann… - Zeitschrift für …, 2008 - Wiley Online Library
Three new thiostannates [Co (C8N5H23)] 2Sn2S6 (I),[Fe (C8N5H23)] 2Sn2S6 (II) and [Ni
(C8N5H23)] 2Sn2S6 (III) were synthesized under solvothermal conditions. In all compounds …

Polar ferromagnetic metal by intercalation of metal–amine complexes

H Zheng, BC Wilfong, D Hickox-Young… - Chemistry of …, 2021 - ACS Publications
The metal–amine complex Co (en) 3, where en= ethylenediamine, intercalates between
layers of cobalt sulfide (CoS) to form a polar, ferromagnetic metal. We solve the structure of …

Template-assisted solvothermal synthesis of five copper (I)− thioantimonate (III) composites: crystal structures and optical and thermal properties of (C6N2H18) 0.5 …

V Spetzler, C Näther, W Bensch - Inorganic chemistry, 2005 - ACS Publications
The novel copper (I)− thioantimonates (III)(C6N2H18) 0.5 Cu2SbS3 (I)(C6N2H16= 1, 6-
diaminohexane),(C4N3H15) 0.5 Cu2SbS3 (II)(C4N3H13= diethylenetriamine),(C8N4H22) …

[TM(en)3][SnSb4S9] (TM = Ni, Co): 3D Chiral Framework of Mixed Main-Group Metals and [Mn(dien)2]2Sb4S9: 1D Chains with Mixed-Valent Sb Centers

CY Yue, XW Lei, YX Ma, N Sheng, YD Yang… - Crystal growth & …, 2014 - ACS Publications
Two new isostructural quaternary tin (IV) antimony (III) sulfides,[TM (en) 3][SnSb4S9][TM= Ni
(1), Co (2); en= ethylenediamine], and one mixed-valent thioantimonate (III and V),[Mn (dien) …

Combined In Situ EDXRD/EXAFS Investigation of the Crystal Growth of [Co(C6H18N4)][Sb2S4] under Solvothermal Conditions:  Two Different Reaction …

R Kiebach, N Pienack, ME Ordolff, F Studt… - Chemistry of …, 2006 - ACS Publications
The crystal growth and kinetics of the formation of [Co (C6H18N4)][Sb2S4] were investigated
under solvothermal conditions with combined in situ EDXRD (energy dispersive X-ray …