Understanding ligand-protected noble metal nanoclusters at work

MF Matus, H Häkkinen - Nature Reviews Materials, 2023 - nature.com
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J Xie - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

N-heterocyclic carbene-stabilized gold nanoclusters with organometallic motifs for promoting catalysis

H Shen, Q Wu, S Malola, YZ Han, Z Xu… - Journal of the …, 2022 - ACS Publications
The complexity of heterogeneous metal catalysts makes it challenging to gain insights into
their catalytic mechanisms. Thus, there exists a huge gap between heterogeneous catalysis …

Synthesis, assembly, and applications of hybrid nanostructures for biosensing

S Zhang, R Geryak, J Geldmeier, S Kim… - Chemical …, 2017 - ACS Publications
The robust, sensitive, and selective detection of targeted biomolecules in their native
environment by prospective nanostructures holds much promise for real-time, accurate, and …

Evolution from the plasmon to exciton state in ligand-protected atomically precise gold nanoparticles

M Zhou, C Zeng, Y Chen, S Zhao, MY Sfeir… - Nature …, 2016 - nature.com
The evolution from the metallic (or plasmonic) to molecular state in metal nanoparticles
constitutes a central question in nanoscience research because of its importance in …

Seeing ligands on nanoclusters and in their assemblies by X-ray crystallography: atomically precise nanochemistry and beyond

Y Li, R Jin - Journal of the American Chemical Society, 2020 - ACS Publications
Ligands are of tremendous importance for colloidal nanoparticles (NPs) in terms of surface
protection, size and shape control, tailoring properties, self-assembly, and applications …

Mechanistic understanding from molecular dynamics simulation in pharmaceutical research 1: drug delivery

A Bunker, T Róg - Frontiers in Molecular Biosciences, 2020 - frontiersin.org
In this review, we outline the growing role that molecular dynamics simulation is able to play
as a design tool in drug delivery. We cover both the pharmaceutical and computational …

Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties

S Hossain, D Hirayama, A Ikeda, M Ishimi… - …, 2023 - Wiley Online Library
Thiolate (SR)‐protected gold nanoclusters (Aun (SR) m NCs) are a rare type of material
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …

Nuclear and electron magnetic resonance spectroscopies of atomically precise gold nanoclusters

M Agrachev, M Ruzzi, A Venzo… - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Atomically precise gold nanoclusters display properties that are unseen in
larger nanoparticles. When the number of gold atoms is sufficiently small, the clusters exhibit …

A dual purpose strategy to endow gold nanoclusters with both catalysis activity and water solubility

Y Zhao, S Zhuang, L Liao, C Wang, N Xia… - Journal of the …, 2019 - ACS Publications
Gold nanoclusters have attracted extensive interest for catalysis applications in recent years
due to their ultrasmall sizes and well-defined compositions and structures. However, at least …