Proton-coupled electron transfer
MHV Huynh, TJ Meyer - Chemical Reviews, 2007 - ACS Publications
At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …
oxidation-reduction reactions in which both electrons and protons are transferred. An …
The remarkable reactivity of high oxidation state ruthenium and osmium polypyridyl complexes
TJ Meyer, MHV Huynh - Inorganic Chemistry, 2003 - ACS Publications
There is a remarkable redox chemistry of higher oxidation state M (IV)− M (VI) polypyridyl
complexes of Ru and Os. They are accessible by proton loss and formation of oxo or nitrido …
complexes of Ru and Os. They are accessible by proton loss and formation of oxo or nitrido …
Coordination, organometallic and related chemistry of tris (pyrazolyl) methane ligands
HR Bigmore, SC Lawrence, P Mountford… - Dalton …, 2005 - pubs.rsc.org
Tris (pyrazolyl) methanes are the neutral analogues of the widely exploited and highly useful
tris (pyrazolyl) hydroborates, yet by comparison with their boron based counterparts their …
tris (pyrazolyl) hydroborates, yet by comparison with their boron based counterparts their …
Structural Snapshots of a Flexible Cu2P2 Core that Accommodates the Oxidation States CuICuI, Cu1.5Cu1.5, and CuIICuII
The phosphido-bridged dicopper (I) complex {(PPP) Cu} 2 has been synthesized and
structurally characterized ([PPP]-= bis (2-di-iso-propylphosphinophenyl) phosphide). Cyclic …
structurally characterized ([PPP]-= bis (2-di-iso-propylphosphinophenyl) phosphide). Cyclic …
Mechanism and Molecular− Electronic Structure Correlations in a Novel Series of Osmium (V) Hydrazido Complexes
MHV Huynh, ES El-Samanody, KD Demadis… - Inorganic …, 2000 - ACS Publications
Reaction between the Os (VI) nitrido (OsVI⋮ N+) complexes [OsVI (L3)(Cl) 2 (N)]+(L3 is 2, 2
': 6 ', 2 ''-terpyridine (tpy) or tris (1-pyrazolyl) methane (tpm)) and secondary amines (HN …
': 6 ', 2 ''-terpyridine (tpy) or tris (1-pyrazolyl) methane (tpm)) and secondary amines (HN …
Formation and Reactivity of the Osmium(IV)–Cyanoimido Complex [OsIV(bpy)(Cl)3(NCN)]−
MHV Huynh, PS White, CA Carter… - Angewandte …, 2001 - Wiley Online Library
Complexes containing the cyanamido (¿ NC¿ NH2),[1] hydrogen cyanamido (¿ N (H)¿
CN¿),[2] and cyanoimido (¿ N¿ CN 2¿)[3] ligands are all known based on coordination of the …
CN¿),[2] and cyanoimido (¿ N¿ CN 2¿)[3] ligands are all known based on coordination of the …
[PDF][PDF] Proton‐Coupled Electron Transfer from Phosphorus: AP− H/P− D Kinetic Isotope Effect of 178
MHV Huynh, TJ Meyer - Angewandte Chemie International Edition, 2002 - academia.edu
In the extensive redox chemistry of high oxidation state ruthenium (iv)±oxo,[1] osmium
(vi)±nitrido,[2] osmium (iv±vi)±hydrazido,[3] osmium (iv)±cyanoimido,[4] and osmium …
(vi)±nitrido,[2] osmium (iv±vi)±hydrazido,[3] osmium (iv)±cyanoimido,[4] and osmium …
Crystal structure and electrochemical behavior of Rh polypyridyl complexes
MY Kim, WK Seok, Y Dong, H Yun - Inorganica Chimica Acta, 2001 - Elsevier
[Rh (tpy)(bpy)(Cl)](ClO4) 2 and [Rh (tpy)(phen)(Cl)](PF6) 2 (tpy; 2, 2′; 6′, 2 ″-terpyridine,
bpy; 2, 2′-bipyridine, phen; 1, 10-phenanthroline) have been determined structurally. Both …
bpy; 2, 2′-bipyridine, phen; 1, 10-phenanthroline) have been determined structurally. Both …
Remarkable rate enhancement of ligand substitution promoted by geometrical arrangement of tridentate “spectator” ligands
MHV Huynh, J Smyth, M Wetzler, B Mort… - Angewandte …, 2001 - Wiley Online Library
Plots of kobs versus [CH3CN] for [RuII (H2O)-(dpp)(tpmm)] 2á and [RuII (H2O)(dpp)(trpy)] 2á
and for [RuII (H2O)(dpp)(tpmm)] 2á and [RuII (H2O)(dop)(tpmm)] 2á were linear with zero …
and for [RuII (H2O)(dpp)(tpmm)] 2á and [RuII (H2O)(dop)(tpmm)] 2á were linear with zero …
Reactivity of dioxoosmium (VI) porphyrins toward arylhydrazine. Isolation of hydrazidoosmium and amidoosmium porphyrins
SKY Leung, JS Huang, N Zhu, CM Che - Inorganic chemistry, 2003 - ACS Publications
Reactions of dioxoosmium (VI) porphyrins [OsVI (Por) O2] with excess 1, 1-
diphenylhydrazine in tetrahydrofuran at ca. 55° C for 15 min afforded bis (hydrazido (1−)) …
diphenylhydrazine in tetrahydrofuran at ca. 55° C for 15 min afforded bis (hydrazido (1−)) …