Screening Hofmann Compounds as CO2 Sorbents: Nontraditional Synthetic Route to Over 40 Different Pore-Functionalized and Flexible Pillared Cyanonickelates

JT Culp, C Madden, K Kauffman, F Shi… - Inorganic …, 2013 - ACS Publications
A simple reaction scheme based on the heterogeneous intercalation of pillaring ligands
(HIPLs) provides a convenient method for systematically tuning pore size, pore functionality …

Effect of polymorphism on the sorption properties of a flexible square-lattice topology coordination network

A Subanbekova, AA Bezrukov, V Bon… - … Applied Materials & …, 2024 - ACS Publications
The stimulus-responsive behavior of coordination networks (CNs), which switch between
closed (nonporous) and open (porous) phases, is of interest because of its potential utility in …

[HTML][HTML] Three structural modifications in the series of layered solids T(H2O)2[Ni(CN)4xH2O with T = Mn, Co, Ni: Their nature and crystal structures

J Rodríguez-Hernández… - Comptes …, 2012 - comptes-rendus.academie-sciences …
Résumé In the studied series of layered solids, the available coordination sites at T metal
centers are occupied by water molecules which serve to stabilize additional water molecules …

π–π interactions and magnetic properties in a series of hybrid inorganic–organic crystals

M González, AA Lemus-Santana… - Journal of solid state …, 2013 - Elsevier
The series of hybrid inorganic–organic solids T (Im) 2 [Ni (CN) 4] with T= Fe, Co, Ni and Im=
imidazole were prepared by soft chemical routes from aqueous solutions of the involved …

Spin crossover in metal–organic framework for improved separation of C2H2/CH4 at room temperature

Y Zheng, J Yong, Z Zhu, J Chen, Z Song… - Journal of Solid State …, 2021 - Elsevier
C 2 H 2 is a very promising fuel substitute in the future, but it is often accompanied by the
presence of CH 4 in its production process, and high-purity C 2 H 2 cannot be obtained. In …

Intermolecular interactions between imidazole derivatives intercalated in layered solids. Substituent group effect

M González, AA Lemus-Santana… - Journal of solid state …, 2013 - Elsevier
This study sheds light on the intermolecular interactions between imidazole derive
molecules (2-methyl-imidazole, 2-ethyl-imidazole and benzimidazole) intercalated in T [Ni …

1-methyl-2-pyrrolidone: from exfoliating solvent to a paramagnetic ligand

AA Lemus-Santana, M González… - The Journal of …, 2013 - ACS Publications
When 1-methyl-2-pyrrolidone molecule (1m2p) interacts with the T [Ni (CN) 4] layer, its
carbonyl π bond homolytically disrupts and forms a coordination bond at the axial positions …

Fast kinetic redox process in layered cobaltous terephthalate MOF-type for aqueous hybrid devices. Magnetic properties as sensor of Co–Co interactions

J Vazquez-Samperio, P Acevedo-Peña… - Electrochimica …, 2020 - Elsevier
The understanding of the fast-redox reactions origin is crucial for developing highly stable
hybrid devices for energy storage. In this work two layered structures were considered …

Dehydration process of Hofmann-type layered solids

O Reyes-Martinez, E Torres-García… - Materials, 2013 - mdpi.com
In the present work the dehydration process of layered solids with formula unit M (H2O) 2 [Ni
(CN) 4]· n H2O, M= Ni, Co, Mn; n= 1, 2, 4 is studied using modulated thermogravimetry. The …

Copper (II) complexes of hindered diazines: methylquinoxalines

CP Landee, MM Turnbull, DA Dickie… - Journal of …, 2024 - Taylor & Francis
Five new copper (II) complexes of substituted quinoxaline ligands have been prepared and
characterized via single crystal X-ray diffraction, including [Cu (5-Mequinox) 2 (NO3) …