Progress in anion receptor chemistry: Chem Skip to Main Content Advertisement Chem This
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Conspectus Proteins exhibit high-binding affinity and selectivity, as well as remarkable
catalytic performance. Their binding pockets are hydrophobic but also contain polar and …

Heteroleptic metal‐organic cages, formed through integrative self‐assembly of ligand
mixtures, are highly attractive as reduced symmetry supramolecular hosts. Ensuring high …

Molecular confinement effects can profoundly alter the physicochemical properties of the
confined species. A plethora of organic molecules were encapsulated within the cavities of …

A strategy is presented that enables the quantitative assembly of a heterobimetallic [PdPtL4]
4+ cage. The presence of two different metal ions (PdII and PtII) with differing labilities …

Confinement within molecular cages can dramatically modify the physicochemical
properties of the encapsulated guest molecules, but such host-guest complexes have mainly …

Described here is a three-component self-assembly system that displays emergent behavior
that differs from that of its constituents. The system comprises an all-hydrocarbon octaaryl …

Coordination cages have been widely reported to bind a variety of guests, which are useful
for chemical separation. Although the use of cages in the solid state benefits the recycling …

Two isomorphous fluorescent (FL) lantern-shaped metal–organic cages 1 and 2 were
prepared by coordination-directed self-assembly of Co (II) centers with a new aza-crown …

While host–guest binding is generally a very fast reaction, guest uptake/release sometimes
becomes slow particularly when the host cavity is separated from the outside by relatively …