Reductive cross-coupling of unreactive electrophiles
X Pang, PF Su, XZ Shu - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Transition-metal-catalyzed reductive coupling of electrophiles has emerged as
a powerful tool for the construction of molecules. While major achievements have been …
a powerful tool for the construction of molecules. While major achievements have been …
Titanium catalysis for the synthesis of fine chemicals–development and trends
M Manßen, LL Schafer - Chemical Society Reviews, 2020 - pubs.rsc.org
Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …
Modern applications of low-valent early transition metals in synthesis and catalysis
Low-valent early transition metals are often intrinsically highly reactive as a result of their
strong propensity toward oxidation to more stable high-valent states. Harnessing these …
strong propensity toward oxidation to more stable high-valent states. Harnessing these …
Radical dehydroxylative alkylation of tertiary alcohols by Ti catalysis
H Xie, J Guo, YQ Wang, K Wang, P Guo… - Journal of the …, 2020 - ACS Publications
Deoxygenative radical C–C bond-forming reactions of alcohols are a long-standing
challenge in synthetic chemistry, and the current methods rely on multistep procedures …
challenge in synthetic chemistry, and the current methods rely on multistep procedures …
Boryl Radical Activation of Benzylic C–OH Bond: Cross-Electrophile Coupling of Free Alcohols and CO2 via Photoredox Catalysis
WD Li, Y Wu, SJ Li, YQ Jiang, YL Li… - Journal of the …, 2022 - ACS Publications
A new strategy for the direct cleavage of the C (sp3)–OH bond has been developed via
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …
[HTML][HTML] Selective deoxygenative alkylation of alcohols via photocatalytic domino radical fragmentations
HM Guo, X Wu - Nature Communications, 2021 - nature.com
The delivery of alkyl radicals through photocatalytic deoxygenation of primary alcohols
under mild conditions is a so far unmet challenge. In this report, we present a one-pot …
under mild conditions is a so far unmet challenge. In this report, we present a one-pot …
Reductive deoxygenative functionalization of alcohols by first‐row transition metal catalysis
X Pang, XZ Shu - Chinese Journal of Chemistry, 2023 - Wiley Online Library
Comprehensive Summary Alcohols are among the most accessible functionalities. Catalytic
deoxygenative functionalization of alcohols is highly synthetically appealing. While …
deoxygenative functionalization of alcohols is highly synthetically appealing. While …
Titanium(IV) Chloride-Catalyzed Photoalkylation via C(sp3)–H Bond Activation of Alkanes
M Yamane, Y Kanzaki, H Mitsunuma, M Kanai - Organic Letters, 2022 - ACS Publications
Despite the sophistication of C–H functionalization as one of the most powerful tools in
organic synthesis, methodology for performing hydrogen-atom transfer of unactivated …
organic synthesis, methodology for performing hydrogen-atom transfer of unactivated …
Ni-catalyzed formal cross-electrophile coupling of alcohols with aryl halides
Q Lin, G Ma, H Gong - ACS Catalysis, 2021 - ACS Publications
Direct coupling of unactivated alcohols remains a challenge in current synthetic chemistry.
We herein demonstrate a strategy building upon in situ halogenation/reductive coupling of …
We herein demonstrate a strategy building upon in situ halogenation/reductive coupling of …
Nickel-catalyzed reductive deoxygenation of diverse C–O bond-bearing functional groups
We report a catalytic method for the direct deoxygenation of various C–O bond-containing
functional groups. Using a Ni (II) pre-catalyst and silane reducing agent, alcohols, epoxides …
functional groups. Using a Ni (II) pre-catalyst and silane reducing agent, alcohols, epoxides …