Click chemistry strategies for the accelerated synthesis of functional macromolecules
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …
materials with precise control over architecture and functionality. In this review, we provide a …
Synthetic strategies, properties, and applications of unsaturated main-chain metallopolymers prepared by olefin metathesis polymerization
Y Sha, H Jia, Z Shen, Z Luo - Polymer Reviews, 2021 - Taylor & Francis
Main-chain metallopolymers are synthesized by olefin metathesis polymerizations. These
polymers are mainly produced through acyclic diene metathesis (ADMET) polymerization …
polymers are mainly produced through acyclic diene metathesis (ADMET) polymerization …
SPAAC iClick: progress towards a bioorthogonal reaction in-corporating metal ions
Combining strain-promoted azide–alkyne cycloaddition (SPAAC) and inorganic click (iClick)
reactivity provides access to metal 1, 2, 3-triazolates. Experimental and computational …
reactivity provides access to metal 1, 2, 3-triazolates. Experimental and computational …
Understanding the solubilization of Ca acetylide with a new computational model for ionic pairs
The unique reactivity of the acetylenic unit in DMSO gives rise to ubiquitous synthetic
methods. We theoretically consider CaC2 solubility and protolysis in DMSO and formulate a …
methods. We theoretically consider CaC2 solubility and protolysis in DMSO and formulate a …
Trapping of Terminal Platinapolyynes by Copper (I) Catalyzed Click Cycloadditions; Probes of Labile Intermediates in Syntheses of Complexes with Extended sp …
H Amini, N Weisbach, S Gauthier… - … A European Journal, 2021 - Wiley Online Library
The silylated hexatriynyl complex trans‐(C6F5)(p‐tol3P) 2Pt (C≡ C) 3SiEt3 (PtC6TES) is
converted in situ to PtC6H (wet n‐Bu4N+ F−, THF) and cross coupled with the diyne H (C≡ …
converted in situ to PtC6H (wet n‐Bu4N+ F−, THF) and cross coupled with the diyne H (C≡ …
Electrospray Mass Spectrometry to Study Combinatorial iClick Reactions and Multiplexed Kinetics of [Ru(N3)(N∧N)(terpy)]PF6 with Alkynes of Different Steric and …
T Zach, F Geyer, B Kiendl, J Mößeler… - Inorganic …, 2023 - ACS Publications
In a combinatorial approach, a family of ruthenium (II) azido complexes [Ru (N3)(N∧
N)(terpy)] PF6 with terpy= 2, 2′: 6′, 2 ″-terpyridine and N∧ N as a bidentate chelator …
N)(terpy)] PF6 with terpy= 2, 2′: 6′, 2 ″-terpyridine and N∧ N as a bidentate chelator …
N^ N^ C platinum (II) complexes based on phenyl-pyridin-2-ylpyrimidine ligands: synthesis, electrochemical and photophysical properties
M Hruzd, S Gauthier, J Boixel, S Kahlal, N Le Poul… - Dyes and …, 2021 - Elsevier
A series of luminescent chloro-and alkynyl-platinum (II) complexes containing various
tridentate cyclometalated ligands derived from phenyl-pyridin-2-ylpyrimidine and alkynyl …
tridentate cyclometalated ligands derived from phenyl-pyridin-2-ylpyrimidine and alkynyl …
C^ N^ N Coordination Accelerates the iClick Reaction of Square-Planar Palladium (II) and Platinum (II) Azido Complexes with Electron-Poor Alkynes and Enables …
K Peng, D Moreth, U Schatzschneider - Organometallics, 2021 - ACS Publications
Organometal azido complexes with a cyclometalating C^ N^ N coligand of the general
formula [M (N3)(phbpy)] with M= Pd (II) or Pt (II) and Hphbpy= 6-phenyl-2, 2′-bipyridine …
formula [M (N3)(phbpy)] with M= Pd (II) or Pt (II) and Hphbpy= 6-phenyl-2, 2′-bipyridine …
iClick synthesis of network metallopolymers
Described is an approach to preparing the first iClick network metallopolymers with porous
properties. Treating digoldazido complex 2-AuN3 with trigoldacetylide 3-AuPPh3 or 3 …
properties. Treating digoldazido complex 2-AuN3 with trigoldacetylide 3-AuPPh3 or 3 …
The iClick Reaction of a BODIPY Platinum(II) Azido Complex with Electron-Poor Alkynes Provides Triazolate Complexes with Good 1O2 Sensitization Efficiency
K Peng, R Einsele, P Irmler, RF Winter… - …, 2020 - ACS Publications
trans-[Pt (bodipy)(N3)(PEt3) 2](bodipy= 4, 4-difluoro-4-bora-3 a, 4 a-diaza-s-indacen-8-yl;
Et= ethyl) reacts with dimethyl acetylenedicarboxylate (DMAD) or F3C–C≡ C–COOEt in a …
Et= ethyl) reacts with dimethyl acetylenedicarboxylate (DMAD) or F3C–C≡ C–COOEt in a …