Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Defect engineering of ZnO: Review on oxygen and zinc vacancies
V Gurylev, TP Perng - Journal of the European Ceramic Society, 2021 - Elsevier
ZnO is an important material which has been widely applied in photodetector, catalyst, gas
sensor, field emitter, etc. Yet, its inability to absorb visible light, poor charge transport, and …
sensor, field emitter, etc. Yet, its inability to absorb visible light, poor charge transport, and …
Molecular Zinc Hydride Cations [ZnH]+: Synthesis, Structure, and CO2 Hydrosilylation Catalysis
Protonolysis of [ZnH2] n with the conjugated Brønsted acid of the bidentate diamine TMEDA
(N, N, N′, N′‐tetramethylethane‐1, 2‐diamine) and TEEDA (N, N, N′, N …
(N, N, N′, N′‐tetramethylethane‐1, 2‐diamine) and TEEDA (N, N, N′, N …
Synthesis and Characterization of Magnesium-Hydride Complexes with Alkylene-Bridged Bis (β-diketiminate) Ligands
P Rinke, H Görls, P Liebing, R Kretschmer - Organometallics, 2023 - ACS Publications
Three magnesium-hydride complexes (3a–c) supported by alkylene-bridged bis (β-
diketiminate) ligands have been synthesized by reacting the respective dinuclear …
diketiminate) ligands have been synthesized by reacting the respective dinuclear …
Metallic barium: a versatile and efficient hydrogenation catalyst
P Stegner, C Färber, U Zenneck, C Knüpfer… - Angewandte …, 2021 - Wiley Online Library
Ba metal was activated by evaporation and cocondensation with heptane. This black
powder is a highly active hydrogenation catalyst for the reduction of a variety of unactivated …
powder is a highly active hydrogenation catalyst for the reduction of a variety of unactivated …
Understanding and Expanding Zinc Cation/Amine Frustrated Lewis Pair Catalyzed C–H Borylation
[(NacNac) Zn (DMT)][B (C6F5) 4], 1,(NacNac={(2, 6-i Pr2H3C6) N (CH3) C} 2CH), DMT= N,
N-dimethyl-4-toluidine), was synthesized via two routes starting from either (NacNac) ZnEt or …
N-dimethyl-4-toluidine), was synthesized via two routes starting from either (NacNac) ZnEt or …
s-Block amidoboranes: syntheses, structures, reactivity and applications
TE Stennett, S Harder - Chemical Society Reviews, 2016 - pubs.rsc.org
Metal amidoborane compounds of the alkali-and alkaline earth metals have in recent years
found applications in diverse disciplines, notably as hydrogen storage materials, as …
found applications in diverse disciplines, notably as hydrogen storage materials, as …
Dipyrromethene and β-diketiminate zinc hydride complexes: resemblances and differences
G Ballmann, S Grams, H Elsen, S Harder - Organometallics, 2019 - ACS Publications
A new dipyrromethene (DPM) ligand with bulky DIPP-substituents is introduced (DIPP= 2, 6-
di iso propylphenyl). The ligand, abbreviated as DIPPDPM, was deprotonated with ZnEt2 to …
di iso propylphenyl). The ligand, abbreviated as DIPPDPM, was deprotonated with ZnEt2 to …
Comparison of Magnesium and Zinc in Cationic π-Arene and Halobenzene Complexes
A Friedrich, J Eyselein, J Langer, S Harder - Organometallics, 2021 - ACS Publications
The reaction of (tBuBDI) ZnEt with [Ph3C+][B (C6F5) 4−] yielded the cation (tBuBDI) Zn+
(tBuBDI= CH [C (t Bu) N-DIPP] 2, DIPP= 2, 6-diisopropylphenyl). The cation is sterically too …
(tBuBDI= CH [C (t Bu) N-DIPP] 2, DIPP= 2, 6-diisopropylphenyl). The cation is sterically too …