The carbamate group is a key structural motif in many approved drugs and prodrugs. There
is an increasing use of carbamates in medicinal chemistry and many derivatives are …

The addition of an organometallic reagent to a carbonyl compound or an imine represents
an important process in synthetic organic chemistry because in this reaction, together with a …

Natural products and small molecules inspired by them are enjoying a resurgence of interest
because they intersect biological space effectively and selectively. On account of their …

During the last century, organometallic reagents prepared from main group metals, 1 such
as organolithium, organomagnesium, and organozinc compounds, have played a central …

From its humble origins as a mere 'chemical curiosity,'radical chemistry has developed into
one of the most powerful tools for preparative organic synthesis. Initially considered too …

Allene (C3H4) gas is produced and separated on million-metric-ton scale per year during
petroleum refining but is rarely employed in organic synthesis. Meanwhile, the addition of an …

N-Formylation of amines or nitroarenes using catalysts is a prominent, chemoselective and
efficient reaction for the fabrication of formyl amides. Formamides are one of the most …

Through the pages of this review, we describe the most important MOFs so far built with the
group 13th elements: indium, gallium and aluminum, with particular emphasis on indium …

The transition metal mediated synthesis of carbon–sulfur (C–S) bonds is possible with a
variety of simple and tailored metal complexes. This chapter serves to illustrate …

A highly practical and efficient asymmetric synthesis of chiral homoallylic amines by In-
mediated allylation of chiral N-tert-butanesulfinyl imines in aqueous media at room …