Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Heteroleptic diimine–diphosphine Cu (I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and …

Y Zhang, M Schulz, M Wächtler, M Karnahl… - Coordination Chemistry …, 2018 - Elsevier
Photoactive Cu (I) complexes are considered as a promising alternative to traditional noble-
metal complexes that are mainly based on Ru (II) and Ir (III). Therefore, in recent years …

Photoredox catalysts based on earth-abundant metal complexes

BM Hockin, C Li, N Robertson… - Catalysis Science & …, 2019 - pubs.rsc.org
Over the last decade, visible light photoredox catalysis has exploded into the consciousness
of the synthetic chemist. The principal photocatalysts used are based on rare and toxic …

Earth-abundant-metal complexes as photosensitizers in molecular systems for light-driven CO2 reduction

F Ma, ZM Luo, JW Wang, BM Aramburu-Trošelj… - Coordination Chemistry …, 2024 - Elsevier
Artificial photosynthesis involving CO 2 photoreduction is an appealing strategy for
addressing environmental and energy-shortage issues. Exploration of cost-efficient …

Recent developments of photoactive Cu (I) and Ag (I) complexes with diphosphine and related ligands

H Takeda, A Kobayashi, K Tsuge - Coordination Chemistry Reviews, 2022 - Elsevier
In the past two decades, emissive Cu (I) complexes have been synthesized with various
ligands, revealing their interesting and useful photophysical properties such as high …

Photochemical CO2 Reduction Driven by Water-Soluble Copper(I) Photosensitizer with the Catalysis Accelerated by Multi-Electron Chargeable Cobalt Porphyrin

X Zhang, M Cibian, A Call, K Yamauchi, K Sakai - ACS Catalysis, 2019 - ACS Publications
Without using precious elements, a highly efficient and selective molecular-based
photocatalytic system for CO2-to-CO conversion in fully aqueous media has been …

Molecular catalysts of Co, Ni, Fe, and Mo for hydrogen generation in artificial photosynthetic systems

WT Eckenhoff - Coordination Chemistry Reviews, 2018 - Elsevier
Driven by population and quality of living increases, the global consumption of energy is
expected to dramatically increase over the course of the century. To avoid meeting this …

Earth-abundant photocatalytic systems for the visible-light-driven reduction of CO 2 to CO

A Rosas-Hernández, C Steinlechner, H Junge… - Green …, 2017 - pubs.rsc.org
Herein, we report a highly selective photocatalytic system, based on an in situ copper
photosensitizer and an iron catalyst, for the reduction of CO2 to CO. Turnover numbers …

Recent progress in homogeneous light-driven hydrogen evolution using first-row transition metal catalysts

A Mazzeo, S Santalla, C Gaviglio, F Doctorovich… - Inorganica Chimica …, 2021 - Elsevier
The rich chemistry, low cost and availability offered by first-row transition metals have
inspired many researchers to focus on the design, preparation and testing of a wide plethora …

Heteroleptic Copper Photosensitizers: Why an Extended π‐System Does Not Automatically Lead to Enhanced Hydrogen Production

M Heberle, S Tschierlei, N Rockstroh… - … A European Journal, 2017 - Wiley Online Library
A series of heteroleptic copper (I) photosensitizers of the type [(P^ P) Cu (N^ N)]+ with an
extended π‐system in the backbone of the diimine ligand has been prepared. The structures …