Structure and solution behaviour of rhodium (I) Vaska-type complexes for correlation of steric and electronic properties of tertiary phosphine ligands
This paper deals with the synthesis of rhodium (I) Vaska-type complexes of the general form
trans-[Rh (CO) X (PX3)](X= halide, X aryl or alkyl substituent) when incorporating tertiary …
trans-[Rh (CO) X (PX3)](X= halide, X aryl or alkyl substituent) when incorporating tertiary …
Structure/reactivity relationships and mechanism from X-ray data and spectroscopic kinetic analysis
The development in crystallography is nothing short of phenomenal, showing an ever
increasing trend towards applications, such as in molecular biology.'Traditional'small …
increasing trend towards applications, such as in molecular biology.'Traditional'small …
Steric vs. electronic anomaly observed from iodomethane oxidative addition to tertiary phosphine modified rhodium (i) acetylacetonato complexes following …
Rhodium (I) acetylacetonato complexes of the formula [Rh (acac)(CO)(PR3)][acac=
acetylacetonate, PR3= PPh31, PCyPh22, PCy2Ph 3, PCy34] were synthesized and the …
acetylacetonate, PR3= PPh31, PCyPh22, PCy2Ph 3, PCy34] were synthesized and the …
Synthetic, electrochemical and structural aspects of a series of ferrocene-containing dicarbonyl β-diketonato rhodium (I) complexes
J Conradie, TS Cameron, MAS Aquino… - Inorganica chimica …, 2005 - Elsevier
Treatment of [Rh (β-diketonato)(cod)] with CO resulted in better yields of [Rh
(FcCOCHCOR)(CO) 2] than by treating [Rh (Cl)(CO) 2] 2 with FcCOCH2COR, R= CF3 …
(FcCOCHCOR)(CO) 2] than by treating [Rh (Cl)(CO) 2] 2 with FcCOCH2COR, R= CF3 …
Activation of Rhenium(I) Toward Substitution in fac-[Re(N,O′-Bid)(CO)3(HOCH3)] by Schiff-Base Bidentate Ligands (N,O′-Bid)
A series of fac-[Re (N, O′-Bid)(CO) 3 (L)](N, O′-Bid= monoanionic bidentate Schiff-base
ligands with N, O donor atoms; L= neutral monodentate ligand) has been synthesized, and …
ligands with N, O donor atoms; L= neutral monodentate ligand) has been synthesized, and …
Kinetic study of the oxidative addition reaction between methyl iodide and [Rh (FcCOCHCOCF3)(CO)(PPh3)]: Structure of [Rh (FcCOCHCOCF3)(CO)(PPh3)(CH3)(I)]
The kinetics of oxidative addition of CH3I to [Rh (FcCOCHCOCF3)(CO)(PPh3)], where Fc=
ferrocenyl and (FcCOCHCOCF3)−= fctfa= ferrocenoylacetonato, have been studied utilizing …
ferrocenyl and (FcCOCHCOCF3)−= fctfa= ferrocenoylacetonato, have been studied utilizing …
Structural correlation between Rh-P and Rh-C bond distances vs. 31P and 13C NMR parameters in monocarbonylphosphinerhodium (I) complexes: Crystal structure …
GJJ Steyn, A Roodt, I Poletaeva… - Journal of organometallic …, 1997 - Elsevier
The crystal structure of (methyl 2-(amino)-1-cyclopentene-1-dithiocarboxylato-κN, κS)-
carbonyl (triphenylphosphine) rhodium (I),[Rh (hacsm)(CO)(PPh3)], was determined. The …
carbonyl (triphenylphosphine) rhodium (I),[Rh (hacsm)(CO)(PPh3)], was determined. The …
Unprecedented N, S, O co-ordination of the doubly deprotonated anion of N-benzoyl-N′-phenylthiourea (H 2 L 2) bridging two rhodium (I) centres: crystal structure of …
Reaction of [Rh (CO) 2Cl] 2 with N-benzoyl-N′-phenylthiourea (H2L2) followed by PPh3
resulted in an unprecedented tridentate (κN′∶ κO, S) bonding mode of the doubly …
resulted in an unprecedented tridentate (κN′∶ κO, S) bonding mode of the doubly …
Synthesis and characterisation of ferrocene-containing β-diketonato complexes of rhodium (I) and rhodium (III)
The synthesis of new β-diketonato rhodium (I) complexes of the type [Rh
(FcCOCHCOR)(CO) 2] and [Rh (FcCOCHCOR)(CO)(PPh3)] with Fc= ferrocenyl and R= Fc …
(FcCOCHCOR)(CO) 2] and [Rh (FcCOCHCOR)(CO)(PPh3)] with Fc= ferrocenyl and R= Fc …
Stereochemistry of the reaction products of the oxidative addition reaction of methyl iodide to [Rh ((C4H3S) COCHCOR)(CO)(PPh3)]: A NMR and computational study …
MM Conradie, J Conradie - Inorganica Chimica Acta, 2009 - Elsevier
A NMR study of the reaction mixture of the square planar [Rh ((C4H3S) COCHCOR)(CO)(
PPh3)] complex and CH3I, where R= CF3, C6H5 or C4H3S, revealed that two types of alkyl …
PPh3)] complex and CH3I, where R= CF3, C6H5 or C4H3S, revealed that two types of alkyl …