Understanding the electric double-layer structure, capacitance, and charging dynamics

J Wu - Chemical Reviews, 2022 - ACS Publications
Significant progress has been made in recent years in theoretical modeling of the electric
double layer (EDL), a key concept in electrochemistry important for energy storage …

Water electrolysis

AJ Shih, MCO Monteiro, F Dattila, D Pavesi… - Nature Reviews …, 2022 - nature.com
Electrochemistry has the potential to sustainably transform molecules with electrons
supplied by renewable electricity. It is one of many solutions towards a more circular …

The 2023 terahertz science and technology roadmap

A Leitenstorfer, AS Moskalenko… - Journal of Physics D …, 2023 - iopscience.iop.org
Terahertz (THz) radiation encompasses a wide spectral range within the electromagnetic
spectrum that extends from microwaves to the far infrared (100 GHz–∼ 30 THz). Within its …

Correlating hydration free energy and specific adsorption of alkali metal cations during CO2 electroreduction on Au

VJ Ovalle, YS Hsu, N Agrawal, MJ Janik… - Nature Catalysis, 2022 - nature.com
Specifically adsorbed alkali metal cations on metal electrodes have been hypothesized to
influence the reduction of CO2. However, experimental detection of these cations during …

The importance of a charge transfer descriptor for screening potential CO2 reduction electrocatalysts

S Ringe - Nature Communications, 2023 - nature.com
It has been over twenty years since the linear scaling of reaction intermediate adsorption
energies started to coin the fields of heterogeneous and electrocatalysis as a blessing and a …

Acidic Hydrogen Evolution Electrocatalysis at High‐Entropy Alloys Correlates with its Composition‐Dependent Potential of Zero Charge

M Kim, E Batsa Tetteh, OA Krysiak… - Angewandte Chemie …, 2023 - Wiley Online Library
The vast possibilities in the elemental combinations of high‐entropy alloys (HEAs) make it
essential to discover activity descriptors for establishing rational electrocatalyst design …

Linking electric double layer formation to electrocatalytic activity

MA Gebbie, B Liu, W Guo, SR Anderson… - ACS …, 2023 - ACS Publications
Electric double layers form at electrode–electrolyte interfaces and often play defining roles in
governing electrochemical reaction rates and selectivity. While double layer formation has …

Complementary probes for the electrochemical interface

E Pastor, Z Lian, L Xia, D Ecija… - Nature Reviews …, 2024 - nature.com
The functions of electrochemical energy conversion and storage devices rely on the
dynamic junction between a solid and a fluid: the electrochemical interface (EI). Many …

Cation modifies interfacial water structures on platinum during alkaline hydrogen electrocatalysis

P Xu, R Wang, H Zhang, V Carnevale… - Journal of the …, 2024 - ACS Publications
The molecular details of an electrocatalytic interface play an essential role in the production
of sustainable fuels and value-added chemicals. Many electrochemical reactions exhibit …

Zooming into the inner Helmholtz plane of Pt (111)–aqueous solution interfaces: chemisorbed water and partially charged ions

J Huang - JACS Au, 2023 - ACS Publications
The double layer on transition metals, ie, platinum, features chemical metal–solvent
interactions and partially charged chemisorbed ions. Chemically adsorbed solvent …