Group contribution-based property estimation methods: advances and perspectives

R Gani - Current Opinion in Chemical Engineering, 2019 - Elsevier
Highlights•A brief overview on the state of the art in group-contribution based property
estimation methods, which are simple methods, easy to use, have some predictive …

Hybrid, interpretable machine learning for thermodynamic property estimation using grammar2vec for molecular representation

V Mann, K Brito, R Gani, V Venkatasubramanian - Fluid Phase Equilibria, 2022 - Elsevier
Property prediction models have been developed for several decades with varying degrees
of performance and complexity, from the group contribution-based methods to molecular …

An evaluation of in-silico methods for predicting solute partition in multiphase complex fluids–A case study of octanol/water partition coefficient

M Turchi, Q Cai, G Lian - Chemical Engineering Science, 2019 - Elsevier
Solute partition in multiphase fluids is an important thermodynamic phenomenon and
performance attribute for a wide range of product formulations of foods, pharmaceuticals and …

Investigation of the structure, stability, and relative solubility of psilocybin in water and pure organic solvents: A molecular simulation study

L Paul, CT Namba-Nzanguim, A Telesphory… - Journal of Molecular …, 2023 - Elsevier
Psilocybin is an indole-based secondary metabolite found naturally in mushrooms which
possesses several pharmacological effects. Recently, a large number of experimental …

Expanding the solubility parameter method mosced to pyridinium-, quinolinium-, pyrrolidinium-, piperidinium-, bicyclic-, morpholinium-, ammonium-, phosphonium …

P Dhakal, AR Weise, MC Fritsch, CM O'Dell… - ACS …, 2020 - ACS Publications
MOSCED (modified separation of cohesive energy density) is a solubility parameter method
that offers an improved treatment of association interactions. Solubility parameter methods …

Predicting the solubility of nonelectrolyte solids using a combination of molecular simulation with the solubility parameter method MOSCED: application to the …

RC Ollier, T Nguyen, H Agarwal, JR Phifer… - Processes, 2022 - mdpi.com
Methods to predict the equilibrium solubility of nonelectrolyte solids are indispensable for
early-stage process development, design, and feasibility studies. Conventional analytic …

MOSCED parameters for 1-n-alkyl-3-methylimidazolium-based ionic liquids: Application to limiting activity coefficients and intuitive entrainer selection for extractive …

P Dhakal, JA Ouimet, SN Roese, AS Paluch - Journal of Molecular Liquids, 2019 - Elsevier
Solubility parameter based methods have long been valuable design tools due to their
ability to make both quantitative predictions and to shed insight into the underlying …

Assessment of the SM12, SM8, and SMD solvation models for predicting limiting activity coefficients at 298.15 K

SN Roese, JD Heintz, CB Uzat, AJ Schmidt… - Processes, 2020 - mdpi.com
The SM x (x= 12, 8, or D) universal solvent models are implicit solvent models which using
electronic structure calculations can compute solvation free energies at 298.15 K. While …

Correlating Pure Component Properties with MOSCED Solubility Parameters: Enthalpy of Vaporization and Vapor Pressure

NH Wong, P Dhakal, SN Roese, AS Paluch - ChemEngineering, 2023 - mdpi.com
Tools to predict vapor–liquid phase equilibria are indispensable for the conceptualization
and design of separation processes. Modified separation of cohesive energy density …

Development of predictive expressions for infinite dilution activity coefficients, molar solubilities and partition coefficients for solutes dissolved in 2-pyrrolidone based …

TI Magsumov, IA Sedov, WE Acree - Journal of Solution Chemistry, 2022 - Springer
A gas chromatographic headspace analysis method was used to experimentally determine
gas-to-liquid partition coefficients and infinite dilution activity coefficients for two saturated (2 …