The bidentate phosphine ligand 1, 2-bis (di-tert-butylphosphinomethyl) benzene (1, 2-
DTBPMB) has been reported over the years as being one of, if not the, best ligands for …

Palladium-catalyzed alkoxycarbonylation reactions allow for the efficient conversion of
widely available unsaturated compounds, CO and alcohols into the corresponding …

The catalytic asymmetric synthesis of P‐chiral phosphorus compounds is an important way
to construct P‐chiral ligands. Herein, we report a new strategy that adopts the pyridinyl …

Mechanistic studies of the catalyst [Pd2 (dba) 3/1, 1′-bis (tert-butyl (pyridin-2-yl)
phosphanyl) ferrocene, L2] for olefin alkoxycarbonylation reactions are described. X-ray …

We report the C− H alkylation of biarylphosphines at the ortho′ position (s) with alkenes by
using rhodium (I) catalysis, which provides straightforward access to a large library of …

The facile construction of C (sp3)‐rich carbo‐and heterocyclic compounds is a pivotal
synthetic strategy to foster contemporary drug discovery programs. The downstream …

An efficient asymmetric hydroesterfication of diarylmethyl carbinols is developed for the first
time with a Pd‐WingPhos catalyst, resulting in a series of chiral 4‐aryl‐3, 4 …

A class of novel diphosphine ligands bearing pyridine substituents was designed and
synthesized for the first time. The resulting palladium complexes of L1 allow for chemo-and …

Hydroesterification of ethylene with carbon monoxide (CO) and methanol (MeOH) for
preparing methyl propionate (MP) has stimulated researcher's attention in recent years …

Palladium-catalysed alkoxycarbonylation of alkenes allows for atom-efficient synthesis of
esters from easily available alkenes in an industrially viable manner. One of the major costs …