Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

High-entropy alloys in electrocatalysis: from fundamentals to applications

JT Ren, L Chen, HY Wang, ZY Yuan - Chemical Society Reviews, 2023 - pubs.rsc.org
High-entropy alloys (HEAs) comprising five or more elements in near-equiatomic
proportions have attracted ever increasing attention for their distinctive properties, such as …

A high-entropy atomic environment converts inactive to active sites for electrocatalysis

H Zhu, S Sun, J Hao, Z Zhuang, S Zhang… - Energy & …, 2023 - pubs.rsc.org
To understand the mechanism of the reaction catalyzed by high-entropy-alloy (HEA)
electrocatalysts, it has become increasingly crucial to investigate the chemical nature of the …

Sabatier Relations in Electrocatalysts Based on High‐entropy Alloys with Wide‐distributed d‐band Centers for Li‐O2 Batteries

J Tian, Y Rao, W Shi, J Yang, W Ning… - Angewandte Chemie …, 2023 - Wiley Online Library
Abstract Li‐O2 battery (LOB) is a promising “beyond Li‐ion” technology with ultrahigh
theoretical energy density (3457 Wh kg− 1), while currently impeded by the sluggish …

Rational design of septenary high-entropy alloy for direct ethanol fuel cells

J Chang, G Wang, C Li, Y He, Y Zhu, W Zhang, M Sajid… - Joule, 2023 - cell.com
Promoting C–C bond cleavage of ethanol by a complete 12-electron (12e) ethanol oxidation
reaction (EOR) is a grand challenge for the development of highly efficient direct ethanol fuel …

Toward controllable and predictable synthesis of high-entropy alloy nanocrystals

YH Liu, CJ Hsieh, LC Hsu, KH Lin, YC Hsiao… - Science …, 2023 - science.org
High-entropy alloy (HEA) nanocrystals have attracted extensive attention in catalysis.
However, there are no effective strategies for synthesizing them in a controllable and …

Joule heating synthesis of well lattice-matched Co2Mo3O8/MoO2 heterointerfaces with greatly improved hydrogen evolution reaction in alkaline seawater electrolysis …

J Sun, S Qin, Z Zhang, C Li, X Xu, Z Li… - Applied Catalysis B …, 2023 - Elsevier
Herein, through a rapid Joule heating method, we have successfully prepared well lattice-
matched Co 2 Mo 3 O 8/MoO 2 heterointerfaces on Ni foam (Co 2 Mo 3 O 8/MoO 2/NF) in …

New Conceptual Catalyst on Spatial High‐Entropy Alloy Heterostructures for High‐Performance Li‐O2 Batteries

P Zhang, X Hui, Y Nie, R Wang, C Wang, Z Zhang… - Small, 2023 - Wiley Online Library
High‐entropy alloys (HEAs) are attracting increased attention as an alternative to noble
metals for various catalytic reactions. However, it is of great challenge and fundamental …

Progress on entropy production engineering for electrochemical catalysis

X Zhang, K Ren, Y Liu, Z Gu, Z Huang, S Zheng… - Acta Physico-Chimica …, 2024 - Elsevier
As for the accurate synthesis of high-performance electrochemical catalysts with good
robustness, the rational design on atomic level is still a priority. Entropy, as one of the most …

High‐entropy nanomaterials for advanced electrocatalysis

SA Lee, J Bu, J Lee, HW Jang - Small Science, 2023 - Wiley Online Library
High‐entropy alloys refer to near‐equimolar alloys of five or more elements and are
receiving attention due to their unique physical and chemical properties. In electrocatalysis …