Metallaheteroboranes with group 16 elements: Aspects of synthesis, framework and reactivity
Metallaheteroborane clusters containing group-16 elements as cluster constituents were
initially of interest solely for the synthesis of high-nuclearity clusters. However, owing to …
initially of interest solely for the synthesis of high-nuclearity clusters. However, owing to …
Metallaboranes and metallaheteroboranes: An overview of single-cage and condensed polyhedral clusters
C Nandi, K Kar, A Roy, S Ghosh - Advances in Inorganic Chemistry, 2023 - Elsevier
Over time, cluster growth reactions for higher nuclearity clusters transformed into the main
goal in polyhedral metallaborane and metallaheteroborane chemistry. Metallaboranes and …
goal in polyhedral metallaborane and metallaheteroborane chemistry. Metallaboranes and …
Cluster Growth Reactions: Structures and Bonding of Metal-Rich Metallaheteroboranes Containing Heavier Chalcogen Elements
C Nandi, A Roy, K Kar, M Cordier, S Ghosh - Inorganic Chemistry, 2022 - ACS Publications
In an effort to synthesize cobalt-rich metallaheteroboranes from decaborane (14) analogues,
we have studied the reaction of 10-vertex nido-[(Cp* Co) 2B6H6E2](Cp*= η5-C5Me5, 1: E …
we have studied the reaction of 10-vertex nido-[(Cp* Co) 2B6H6E2](Cp*= η5-C5Me5, 1: E …
Synthesis, structures and bonding of group 6 thio-complexes
S Mohapatra, A Haridas, M Kumar, S Ghosh - Inorganica Chimica Acta, 2024 - Elsevier
The structures and bonding of polythio complexes having group 6 metals are described. A
trinuclear tungsten mixed valance complex,[{Cp* WCl (μ-S) 2} 2 WO], 1 along with known …
trinuclear tungsten mixed valance complex,[{Cp* WCl (μ-S) 2} 2 WO], 1 along with known …
Syntheses, structures, and bonding of boron containing niobium and ruthenium clusters stabilized by chalcogens
S Bairagi, D Chatterjee, A De, M Cordier… - Journal of …, 2024 - Elsevier
In an effort to synthesize niobaheteroboranes and ruthenaheteroboranes, two different
synthetic methods are developed. The reactions of [Cp* NbCl 4](1) with chalcogenaborate …
synthetic methods are developed. The reactions of [Cp* NbCl 4](1) with chalcogenaborate …
Chemistry of CS2 and CS3 Bridged Decaborane Analogues: Regular Coordination Versus Cluster Expansion
In an effort to synthesize metallaheteroborane clusters of higher nuclearity, the reactivity of
metallaheteroboranes, nido-[(Cp* M) 2B6S2H4 (CS3)](Cp*= C5Me5)(1: M= Co; 2: M= Rh) …
metallaheteroboranes, nido-[(Cp* M) 2B6S2H4 (CS3)](Cp*= C5Me5)(1: M= Co; 2: M= Rh) …