Dearomatization reactions provide rapid access to structurally complex three-dimensional
molecules from simple aromatic compounds. Plenty of reports have demonstrated their …

Dearomatization reactions provide a synthetic connection between readily available, simple
aromatic starting materials and more saturated intermediates of greater molecular …

Vicinal diamines, especially unsymmetrical ones, are among the most common structural
motifs in biologically active molecules, natural products and pharmaceuticals. While the …

Dearomative photocycloaddition of monocyclic arenes is an appealing strategy for
comprehending the concept of “escape from flatland”. This brings the replacement of readily …

Hybrid fused two-dimensional/three-dimensional (2D/3D) rings are important
pharmacophores in drugs owing to their unique structural and physicochemical properties …

Herein, a metal-free electrochemical dihydroxylation of unactivated alkenes is described.
The transformation proceeds smoothly under mild conditions with a broad range of …

Arene hydrogenation provides direct access to saturated carbo‐and heterocycles and thus
its strategic application may be used to shorten synthetic routes. This powerful …

Dearomatization is a fundamental chemical transformation, and it underlies some of the
most efficient tactics for generating three-dimensional complexity from basic two …

Recent developments of stereoselective biocatalytic and chemocatalytic methods are
discussed. The review provides a guide to the use of biocatalytic methods in the area of …

Dearomative cycloaddition is a powerful technique to access sp3-rich three-dimensional
structural motifs from simple flat, aromatic feedstock. The building-up of unprecedentedly …