Insight into the selectivity of nano-catalytic nitroarenes reduction over other active groups by exploring hydrogen sources and metal components

ZN Hu, J Liang, K Ding, Y Ai, Q Liang, H Sun - Applied Catalysis A: General, 2021 - Elsevier
Catalytic reduction of nitroarenes to the corresponding anilines is a crucial reaction in the
fine and bulk chemical industry, however, the control of chemoselectivity remains enormous …

Controlled and Chemoselective Hydrogenation of Nitrobenzene over Ru@C60 Catalysts

F Leng, IC Gerber, P Lecante, S Moldovan… - ACS …, 2016 - ACS Publications
Electron-deficient ruthenium nanoparticles supported on Ru fulleride nanospheres allow the
successive and chemoselective hydrogenation of nitrobenzene to aniline and then to …

Concurrent hydrogenation of aromatic and nitro groups over carbon-supported ruthenium catalysts

P Tomkins, E Gebauer-Henke, W Leitner… - ACS …, 2015 - ACS Publications
The concurrent hydrogenation of aromatic and nitro groups poses particular challenges due
to the highly differing adsorption strengths of the two chemical moieties on the surfaces of …

Ni-Catalyzed reductive amination of phenols with ammonia or amines into cyclohexylamines

T Cuypers, T Morias, S Windels, C Marquez… - Green …, 2020 - pubs.rsc.org
Phenol and its derivatives, which naturally occur in lignocellulose, can be considered as a
renewable feedstock not only for aromatic, but also for alicyclic compounds, such as primary …

Insight into the role of additives in catalytic synthesis of cyclohexylamine from nitrobenzene

X Li, Z Wang, S Mao, Y Chen, M Tang… - Chinese Journal of …, 2018 - Wiley Online Library
Cyclohexylamine is a versatile intermediate in various chemical industries, which can be
expediently synthesized via hydrogenation of aniline or nitrobenzene. However, such …

Ru/gC 3 N 4 as an efficient catalyst for selective hydrogenation of aromatic diamines to alicyclic diamines

J Cao, F Han, L Wang, X Huang, Y Cao, P He… - RSC …, 2020 - pubs.rsc.org
A series of Ru/g-C3N4 materials with highly dispersed Ru were firstly prepared by an
ultrasonic impregnation method using carbon nitride as a support. The catalysts were …

Enhanced Selectivity in the Hydrogenation of Anilines to Cyclo‐aliphatic Primary Amines over Lithium‐Modified Ru/CNT Catalysts

P Tomkins, TE Müller - ChemCatChem, 2018 - Wiley Online Library
The hydrogenation of aromatic amines to the corresponding cycloaliphatic primary amines is
an important industrial reaction. However, secondary amine formation and other side …

Hydrogenation and Hydrogenolysis with ruthenium catalysts and application to biomass conversion

TE Müller - Ruthenium: An Element Loved by Researchers, 2021 - books.google.com
With the rising emphasis on efficient and highly selective chemical transformations, the field
of ruthenium-catalysed hydrogenation and hydrogenolysis reactions has grown …

Molecular assembly line: Stepwise hydrogenation of multifunctional substrates over catalyst mixtures

P Tomkins, E Gebauer‐Henke, TE Müller - ChemCatChem, 2016 - Wiley Online Library
The synthesis of many chemical products requires multiple steps. To simplify the overall
synthesis by combining consecutive reaction steps, the concept of a “molecular assembly …

The distinct role of the flexible polymer matrix in catalytic conversions over immobilised nanoparticles

S Martinuzzi, D Cozzula, P Centomo, M Zecca… - RSC Advances, 2015 - pubs.rsc.org
Polymer resins with immobilized metal nanoparticles represent highly promising materials
for attaining intelligent and ecologically friendly catalysts. Control of the dynamic swelling …