Best practices for experiments and reporting in photocatalytic CO2 reduction

M Bonchio, J Bonin, O Ishitani, TB Lu, T Morikawa… - Nature Catalysis, 2023 - nature.com
Visible-light-driven conversion of CO2 to fuels and valuable compounds has experienced
tremendous activity in recent years, aiming at storing solar energy into chemical bonds using …

Understanding the Role of Inter- and Intramolecular Promoters in Electro- and Photochemical CO2 Reduction Using Mn, Re, and Ru Catalysts

E Fujita, DC Grills, GF Manbeck… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus Recycling of carbon dioxide to fuels and chemicals is a promising strategy for
renewable energy storage. Carbon dioxide conversion can be achieved by (i) artificial …

Earth-Abundant Photocatalytic CO2 Reduction by Multielectron Chargeable Cobalt Porphyrin Catalysts: High CO/H2 Selectivity in Water Based on Phase Mismatch …

X Zhang, K Yamauchi, K Sakai - ACS Catalysis, 2021 - ACS Publications
To stop global warming and climate changes, substantial efforts have been made to
diminish CO2 emission. Photocatalytic and electrocatalytic CO2 reduction into fuels has thus …

Visible-Light-Driven Photocatalytic CO2 Reduction by Re(I) Photocatalysts with N-Heterocyclic Substituents

AV Müller, LA Faustino, KT de Oliveira… - ACS …, 2022 - ACS Publications
The properties and reactivity of metal complex photocatalysts for solar-to-fuel conversion
can be conveniently controlled by the molecular design of their ligands. In this work, rhenium …

Role of Bimetallic Interactions in the Enhancement of Catalytic CO2 Reduction by a Macrocyclic Cobalt Catalyst

DE Polyansky, DC Grills, MZ Ertem, KT Ngo… - ACS …, 2022 - ACS Publications
The use of two metal centers in a CO2 reduction catalyst that work together synergistically,
with similar or complementary functions, can potentially lead to a significant reduction in …

Photocatalytic Reduction of CO2 to CO in Aqueous Solution under Red-Light Irradiation by a Zn-Porphyrin-Sensitized Mn(I) Catalyst

J Shipp, S Parker, S Spall, SL Peralta-Arriaga… - Inorganic …, 2022 - ACS Publications
This work demonstrates photocatalytic CO2 reduction by a noble-metal-free photosensitizer-
catalyst system in aqueous solution under red-light irradiation. A water-soluble Mn (I) …

[AsCCAs]-Coordinated Rhenium Hydrides and Their Reactivities Toward Unsaturated Hydrocarbons, Heterocumulenes, and CO2

L Eberle, F Kreis, CAM Stein, JM Mörsdorf… - Inorganic …, 2023 - ACS Publications
An [AsCCAs] ligand featuring a central alkyne and two flanking arsenic donors was
employed for the synthesis of a trihydrido rhenium complex, while the corresponding …

Bright or Dark: Unexpected Photocatalytic Behavior of Closely Related Phenanthroline‐based Copper (I) Photosensitizers

F Doettinger, M Obermeier, V Caliskanyürek… - …, 2023 - Wiley Online Library
In search of a better understanding of the structure‐property relationship of heteroleptic CuI
photosensitizers, two structurally closely related complexes are investigated in detail …

Manipulating the Reaction Pathway of CO2 Photoreduction via the Microenvironment of a Re Molecular Catalyst

Z Su, Y Luo, J Shi, J Feng, X Li, J Zhang… - The Journal of Physical …, 2023 - ACS Publications
Re molecular complexes incorporated into two metal–organic frameworks were investigated
to disclose the host–guest interaction by infrared and 1H nuclear magnetic resonance and to …

Single Site W(0) versus Re(I)‐Dipyridophenazine‐ Based Conjugated Porous Polymer for CO2 Photoreduction

Á Matarín, F Sánchez, L Collado, M Barawi… - Small …, 2024 - Wiley Online Library
Herein, the synthesis and characterization of two robust tungsten and rhenium carbonyl
complexes integrated into an organic polymer (CPP‐Re, CPP‐W) are reported. These …