Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

TW van Deelen, C Hernández Mejía, KP de Jong - Nature Catalysis, 2019 - nature.com
Metal nanoparticles stabilized on a support material catalyse many major industrial
reactions. Metal-support interactions in these nanomaterials can have a substantial …

Dynamic interplay between metal nanoparticles and oxide support under redox conditions

H Frey, A Beck, X Huang, JA van Bokhoven… - Science, 2022 - science.org
The dynamic interactions between noble metal particles and reducible metal-oxide supports
can depend on redox reactions with ambient gases. Transmission electron microscopy …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Self‐accommodation induced electronic metal–support interaction on ruthenium site for alkaline hydrogen evolution reaction

C Li, SH Kim, HY Lim, Q Sun, Y Jiang… - Advanced …, 2023 - Wiley Online Library
Tuning the metal‐support interaction of supported metal catalysts has been found to be the
most effective approach to modulating electronic structure and improving catalytic …

Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites

Z Li, S Ji, Y Liu, X Cao, S Tian, Y Chen, Z Niu… - Chemical …, 2019 - ACS Publications
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …

The critical impacts of ligands on heterogeneous nanocatalysis: A review

L Lu, S Zou, B Fang - ACS Catalysis, 2021 - ACS Publications
Ligand utilization is a necessary and powerful technique for the colloidal synthesis of
nanoparticles (NPs) with controllable sizes and regulated morphologies. For catalysis …

Structure Sensitivity of Au‐TiO2 Strong Metal–Support Interactions

Y Zhang, JX Liu, K Qian, A Jia, D Li… - Angewandte Chemie …, 2021 - Wiley Online Library
Strong metal–support interactions (SMSI) is an important concept in heterogeneous
catalysis. Herein, we demonstrate that the Au‐TiO2 SMSI of Au/TiO2 catalysts sensitively …

Boosting CO2 hydrogenation via size-dependent metal–support interactions in cobalt/ceria-based catalysts

A Parastaev, V Muravev, E Huertas Osta… - Nature Catalysis, 2020 - nature.com
Metal–support interactions have a strong impact on the performance of heterogeneous
catalysts. Specific sites at the metal–support interface can give rise to unusual high …

Reaction-induced strong metal–support interactions between metals and inert boron nitride nanosheets

J Dong, Q Fu, H Li, J Xiao, B Yang… - Journal of the …, 2020 - ACS Publications
Encapsulation of metal nanocatalysts by support-derived materials is well known as a
classical strong metal–support interaction (SMSI) effect that occurs almost exclusively with …