Thermocatalytic formic acid dehydrogenation: recent advances and emerging trends

R Xu, W Lu, S Toan, Z Zhou, CK Russell… - Journal of Materials …, 2021 - pubs.rsc.org
As a state-of-the-art resource for in situ hydrogen supply, formic acid has recently attracted
considerable attention due to its advantages of high hydrogen content, low toxicity, and easy …

Catalysis in solid hydrogen storage: recent advances, challenges, and perspectives

MS Salman, C Pratthana, Q Lai, T Wang… - Energy …, 2022 - Wiley Online Library
Catalysis is at the core of previous energy transition. It has enabled the use of oil and natural
gas as our primary energy sources in unprecedented ways and led to feedstocks enabling …

Fast dehydrogenation of formic acid over palladium nanoparticles immobilized in nitrogen-doped hierarchically porous carbon

Q Wang, N Tsumori, M Kitta, Q Xu - ACS Catalysis, 2018 - ACS Publications
In this work, a hierarchically porous carbon was prepared from carbonization of a nitrogen-
containing metal–organic framework, followed by activation under ultrasonication in …

Catalysis in liquid organic hydrogen storage: recent advances, challenges, and perspectives

MS Salman, N Rambhujun, C Pratthana… - Industrial & …, 2022 - ACS Publications
With the renewed interest for hydrogen as an energy carrier, means to produce, but most
importantly store, transport, and distribute,“green” hydrogen over long distances has …

[HTML][HTML] Fuelling the hydrogen economy: Scale-up of an integrated formic acid-to-power system

R van Putten, T Wissink, T Swinkels… - international journal of …, 2019 - Elsevier
Transitioning from fossil fuels to sustainable and green energy sources in mobile
applications is a difficult challenge and demands sustained and highly multidisciplinary …

Base-free reversible hydrogen storage using a tethered π-coordinated-phenoxy ruthenium-dimer precatalyst

R Verron, E Puig, P Sutra, A Igau, C Fischmeister - ACS Catalysis, 2023 - ACS Publications
A dimeric tethered π-coordinated-phenoxy ruthenium precatalyst has been used for the
base-free hydrogenation of CO2 in DMSO. The same precatalyst was also efficient in the …

Single-Site Iridium Picolinamide Catalyst Immobilized onto Silica for the Hydrogenation of CO2 and the Dehydrogenation of Formic Acid

L Tensi, AV Yakimov, C Trotta, C Domestici… - Inorganic …, 2022 - ACS Publications
The development of an efficient heterogeneous catalyst for storing H2 into CO2 and
releasing it from the produced formic acid, when needed, is a crucial target for overcoming …

Hydrogen production from formic acid catalyzed by a phosphine free manganese complex: investigation and mechanistic insights

A Léval, A Agapova, C Steinlechner, E Alberico… - Green …, 2020 - pubs.rsc.org
Formic acid dehydrogenation (FAD) is considered as a promising process in the context of
hydrogen storage. Its low toxicity, availability and convenient handling make FA attractive as …

Recent Developments in Reversible CO2 Hydrogenation and Formic Acid Dehydrogenation over Molecular Catalysts

S Kushwaha, J Parthiban, SK Singh - ACS omega, 2023 - ACS Publications
Carbon dioxide (CO2), a valuable feedstock, can be reutilized as a hydrogen carrier by
hydrogenating CO2 to formic acid (FA) and releasing hydrogen by FA dehydrogenation in a …

Reactivity of heterobimetallic ion pairs in formic acid dehydrogenation

ES Osipova, DV Sedlova, EI Gutsul… - …, 2023 - ACS Publications
The series of bimetallic complexes (t BuPXCYP) Pd (μ-OC) M (CO) 2L (X, Y= CH2, O; M= W,
Mo; L= Cp, Tp) catalyzes formic acid decomposition into H2/CO2 in fairly mild conditions (25 …