Heterogeneity in single-molecule observables in the study of supercooled liquids

LJ Kaufman - Annual review of physical chemistry, 2013 - annualreviews.org
Bulk approaches to studying heterogeneous systems obscure important details, as they
report average behavior rather than the distribution of behaviors in such environments …

Construction of emission-tunable nanoparticles based on a TICT-AIEgen: Impact of aggregation-induced emission versus twisted intramolecular charge transfer

YC Chiang, ZL Lai, CM Chen, CC Chang… - Journal of Materials …, 2018 - pubs.rsc.org
Traditional fluorogens with aggregation-induced emission (AIEgens) generally exhibit strong
luminescence with monotonous wavelengths in the aggregated state, whereas apparent …

Excitation spectra and Stokes shift measurements of single organic dyes at room temperature

MHW Stopel, C Blum… - The journal of physical …, 2014 - ACS Publications
We report measurements of excitation and emission spectra of single, polymer-embedded,
perylene dye molecules at room temperature. From these measurements, we can derive the …

Single molecule studies on dynamics in liquid crystals

D Täuber, C Von Borczyskowski - International Journal of Molecular …, 2013 - mdpi.com
Single molecule (SM) methods are able to resolve structure related dynamics of guest
molecules in liquid crystals (LC). Highly diluted small dye molecules on the one hand …

Influence of van der Waals interactions on morphology and dynamics in ultrathin liquid films at silicon oxide interfaces

D Täuber, I Trenkmann, C Von Borczyskowski - Langmuir, 2013 - ACS Publications
Single molecule tracer diffusion studies of evaporating (thinning) ultrathin tetrakis-2-ethyl-
hexoxysilane (TEHOS) films on silicon with 100 nm thermal oxide reveal a considerable …

Influence of the glass transition on rotational dynamics of dyes in thin polymer films: Single-molecule and ensemble experiments

B Araoz, A Carattino, D Tauber… - The Journal of …, 2014 - ACS Publications
We performed polarized fluorescence emission studies of Nile Red (NR) in poly (methyl
methacrylate)(PMMA), poly (ethyl methacrylate)(PEMA), and poly (butyl …

Fluorescence correlation spectroscopy in thin films at reflecting substrates as a means to study nanoscale structure and dynamics at soft-matter interfaces

D Täuber, K Radscheit, C Von Borczyskowski… - Physical Review E, 2016 - APS
Structure and dynamics at soft-matter interfaces play an important role in nature and
technical applications. Optical single-molecule investigations are noninvasive and capable …

Multicolour single molecule emission and excitation spectroscopy reveals extensive spectral shifts

L Piatkowski, E Gellings, NF van Hulst - Faraday Discussions, 2015 - pubs.rsc.org
We explore the distribution and shape of single molecule spectra at room temperature, when
embedded in a polymer host. Multicolour excitation and emission spectroscopy is …

A multi-property fluorescent probe for the investigation of polymer dynamics near the glass transition

J Siekierzycka, C Hippius, F Würthner, R Williams… - Open …, 2014 - degruyter.com
In addition to the commonly observed single molecule fluorescence intensity fluctuations
due to molecular reorientation dynamics, a perylene bisimide-calixarene compound (1) …