Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Synergistic dual transition metal catalysis

UB Kim, DJ Jung, HJ Jeon, K Rathwell… - Chemical Reviews, 2020 - ACS Publications
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to
enable a reaction between two separately activated substrates, has unlocked a plethora of …

Divergent gold catalysis: unlocking molecular diversity through catalyst control

CC Chintawar, AK Yadav, A Kumar… - Chemical …, 2021 - ACS Publications
The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

The interplay of carbophilic activation and Au (I)/Au (III) catalysis: an emerging technique for 1, 2-difunctionalization of C–C multiple bonds

VW Bhoyare, AG Tathe, A Das, CC Chintawar… - Chemical Society …, 2021 - pubs.rsc.org
Gold complexes have emerged as the catalysts of choice for various functionalization
reactions of C–C multiple bonds due to their inherent carbophilic nature. In a parallel space …

Challenges and opportunities in multicatalysis

S Martínez, L Veth, B Lainer, P Dydio - ACS Catalysis, 2021 - ACS Publications
Multicatalysis is an emerging field targeting the development of efficient catalytic
transformations to quickly convert relatively simple starting materials into more complex …

Organocatalysis in inert C–H bond functionalization

Y Qin, L Zhu, S Luo - Chemical reviews, 2017 - ACS Publications
As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

Complete field guide to asymmetric BINOL-phosphate derived Brønsted acid and metal catalysis: history and classification by mode of activation; Brønsted acidity …

D Parmar, E Sugiono, S Raja, M Rueping - Chemical reviews, 2014 - ACS Publications
The activation of a substrate by a chiral catalyst is now regarded as one of the most powerful
strategies that can be employed in the art of asymmetric synthesis. 1 The development of …

Combinations of aminocatalysts and metal catalysts: a powerful cooperative approach in selective organic synthesis

S Afewerki, A Cordova - Chemical reviews, 2016 - ACS Publications
The cooperation and interplay between organic and metal catalyst systems is of utmost
importance in nature and chemical synthesis. Here innovative and selective cooperative …

Asymmetric organocatalysis combined with metal catalysis: concept, proof of concept, and beyond

DF Chen, ZY Han, XL Zhou… - Accounts of chemical …, 2014 - ACS Publications
Conspectus Asymmetric catalysis has been considered to be the most intriguing means for
building collections of functionalized optically active compounds. In particular, metal and …

Combining transition metal catalysis and organocatalysis–an update

Z Du, Z Shao - Chemical Society Reviews, 2013 - pubs.rsc.org
The combination of transition metal catalysis and organocatalysis as a new and exciting
research area has attracted increasing attention as it can enable the development of …