Recent advances in the chemistry of isolable carbene analogues with group 13–15 elements
Carbenes (R2C:), compounds with a divalent carbon atom containing only six valence shell
electrons, have evolved into a broader class with the replacement of the carbene carbon or …
electrons, have evolved into a broader class with the replacement of the carbene carbon or …
The aluminyl anion: a new generation of aluminium nucleophile
Trivalent aluminium compounds are well known for their reactivity as Lewis
acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and …
acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and …
The road travelled: after main‐group elements as transition metals
Since the latter quarter of the twentieth century, main group chemistry has undergone
significant advances. Power's timely review in 2010 highlighted the inherent differences …
significant advances. Power's timely review in 2010 highlighted the inherent differences …
The unique β-diketiminate ligand in aluminum (I) and gallium (I) chemistry
M Zhong, S Sinhababu, HW Roesky - Dalton Transactions, 2020 - pubs.rsc.org
Over the past few decades, β-diketiminate ligands have been widely used in coordination
chemistry and are capable of stabilizing various metal complexes in multiple oxidation …
chemistry and are capable of stabilizing various metal complexes in multiple oxidation …
Boosting Low‐Valent Aluminum (I) Reactivity with a Potassium Reagent
S Grams, J Eyselein, J Langer, C Färber… - Angewandte …, 2020 - Wiley Online Library
Abstract The reagent RK [R= CH (SiMe3) 2 or N (SiMe3) 2] was expected to react with the
low‐valent (DIPPBDI) Al (DIPPBDI= HC [C (Me) N (DIPP)] 2, DIPP= 2, 6‐iPr‐phenyl) to give …
low‐valent (DIPPBDI) Al (DIPPBDI= HC [C (Me) N (DIPP)] 2, DIPP= 2, 6‐iPr‐phenyl) to give …
Probing the extremes of covalency in M− Al bonds: lithium and zinc aluminyl compounds
Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing
for the first structural characterization of an unsupported lithium–aluminium bond …
for the first structural characterization of an unsupported lithium–aluminium bond …
The Monomeric Alanediyl :AlAriPr8 (AriPr8 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2): An Organoaluminum(I) Compound with a One-Coordinate …
JD Queen, A Lehmann, JC Fettinger… - Journal of the …, 2020 - ACS Publications
Reduction of the aluminum iodide AlI2Ar i Pr8 (1; Ar i Pr8= C6H-2, 6-(C6H2-2, 4, 6-Pr i 3) 2-
3, 5-Pr i 2) with 5% w/w Na/NaCl in hexanes gave a dark red solution from which the …
3, 5-Pr i 2) with 5% w/w Na/NaCl in hexanes gave a dark red solution from which the …
Nickel‐Catalyzed Selective C(sp2)−F Bond Alkylation of Industrially Relevant Hydrofluoroolefin HFO‐1234yf
YC Luo, MK Wang, LC Yu… - Angewandte Chemie …, 2023 - Wiley Online Library
The selective transition‐metal catalyzed C− F bond functionalization of inexpensive
industrial fluorochemicals represents one of the most attractive approaches to valuable …
industrial fluorochemicals represents one of the most attractive approaches to valuable …
Cleavage of C(sp3)–F Bonds in Trifluoromethylarenes Using a Bis(NHC)nickel(0) Complex
H Iwamoto, H Imiya, M Ohashi… - Journal of the American …, 2020 - ACS Publications
The first example of the oxidative addition of a C (sp3)–F bond in trifluoromethylarenes to a
nickel (0) complex is described. A nickel (0) complex that bears two N-heterocyclic carbene …
nickel (0) complex is described. A nickel (0) complex that bears two N-heterocyclic carbene …
Recent advances in low oxidation state aluminium chemistry
The synthesis and isolation of novel low oxidation state aluminium (Al) compounds has seen
relatively slow progress over the 30 years since such species were first isolated. This is …
relatively slow progress over the 30 years since such species were first isolated. This is …