[HTML][HTML] Why standard electrokinetic analysis often fails for nanostructured electrodes-reviewing inhomogeneous electroactivity

P Cignoni, N Blanc, K Tschulik - Current Opinion in Electrochemistry, 2023 - Elsevier
The advancement of electrocatalysis from fundamental research to application is a process
that requires researchers from different fields to co-work seamlessly to be effective. In this …

A simple and effective method for the accurate extraction of kinetic parameters using differential Tafel plots

P Khadke, T Tichter, T Boettcher, F Muench… - Scientific reports, 2021 - nature.com
The practice of estimating the transfer coefficient (α) and the exchange current (i 0) by
arbitrarily placing a straight line on Tafel plots has led to high variance in these parameters …

Discovering Electrochemistry with an Electrochemistry‐Informed Neural Network (ECINN)

H Chen, M Yang, B Smetana, V Novák… - Angewandte …, 2024 - Wiley Online Library
Abstract Machine learning is increasingly integrated into chemistry research by guiding
experimental procedures, correlating structure and function, interpreting large experimental …

Fluidized nanoparticles catalyzed oxygen evolution reaction: Enhanced stability, kinetics and electrocatalytic activity

D Song, H Yan, W Xu, YG Zhou - Chemical Engineering Journal, 2023 - Elsevier
Catalyst stability, reaction kinetics and electrocatalytic activity are significant issues in
electrocatalysis. In this work, OER is examined by a fluidized working mode using RuO 2 …

Influence of conductive porous electrodes on the apparent electrode kinetics of fenitrothion

K Jangid, R Gupta, RP Sahu, I Zhitomirsky… - Journal of …, 2022 - Elsevier
Planar bare electrodes fabricated with surface-modified multiwalled carbon nanotubes
(MWCNT) are used to detect organophosphate (OP) compounds, which are used as …

Sub-and super-Nernstian Tafel slopes can result from reversible electron transfer coupled to either preceding or following chemical reaction

H Chen, RG Compton - Journal of Electroanalytical Chemistry, 2021 - Elsevier
A general scheme for an electrochemically reversible one-electron electrode reaction
containing both preceding and following coupled chemical kinetics is analysed in the light of …

How to extract kinetic information from Tafel analysis in electrocatalysis

W Wu, Q Lu, G Li, Y Wang - The Journal of Chemical Physics, 2023 - pubs.aip.org
Electrocatalysis has become increasingly attractive in aiding transformation to green
chemical industries. Proper evaluation and in-depth understanding of electrocatalysts are …

Mass Transport Influence in the SO2 Oxidation Reaction on Au Electrodes

LD De Angelis, SI Córdoba de Torresi… - …, 2023 - Wiley Online Library
The use of fossil fuels as energy source is unsustainable in the long term and net‐zero
carbon processes need to be implemented to maintain environmental balance. One could …

Anodic processes in the alkaline Cu| Cu (II), glycine system—construction and analysis of mass transport–corrected Tafel plots

A Survila, S Kanapeckaitė, L Staišiūnas - Journal of Solid State …, 2023 - Springer
The anodic behavior of the alkaline Cu| Cu (II), glycine system was investigated by RDE
voltammetry combined with EQCM measurements. Well-defined current plateaus were …

Derivative-extremum analysis of current-potential curves showing electrochemical kinetics in the full reversibility range

F Yin, H Liu - Chinese Chemical Letters, 2023 - Elsevier
Derivative-extremum analysis (DEA) of jE curves is a newly proposed method of half wave
potential (E 1/2) and activation feature extraction from steady-state voltammetry. Here, the …