Enhancement of H2 physisorption in covalent organic Framework's linkers by Li-decoration

H Joshi, S Pakhira - International Journal of Hydrogen Energy, 2024 - Elsevier
Our rigorous investigation, employing first principles-based dispersion-corrected density
functional theory (DFT-D) and second-order Møller-Plesset perturbation theory (MP2) …

Shaping the Future of Green Hydrogen Production: Overcoming Conventional Challenges with Molecular Catalysts, Immobilization, and Scalable Electrolyzers

S Karim, N Tanwar, S Das, R Ranjit, A Banerjee… - ACS …, 2025 - ACS Publications
The energy crisis is a daunting global problem that calls for innovative and supportable
solutions to ensure future energy security and environmental stability. To counter this energy …

Investigating CO2 electro-reduction mechanisms: DFT insight into earth-abundant Mn diimine catalysts for CO2 conversions over hydrogen evolution reaction …

M Panneerselvam, M Albuquerque… - Frontiers of Chemical …, 2024 - Springer
This study investigates the detailed mechanism of CO2 conversion to CO using the
manganese (I) diimine electrocatalyst [Mn (pyrox)(CO) 3Br], synthesized by Christoph …

Role of the Quantum Interactions in H2 Adsorption on Late Transition Metal Chelated Linkers of Covalent Organic Frameworks

H Joshi, S Pakhira - ChemPhysChem - Wiley Online Library
Transition metal (Tm) chelation is an effective strategy to achieve optimal binding enthalpy
(▵ H) of H2‐adsorption in the linkers of covalent organic frameworks (COFs). The first …