Cross-electrophile coupling (XEC) reactions of aryl and alkyl electrophiles are appealing but
limited to specific substrate classes. Here, we report electroreductive XEC of previously …

The development of catalytic carbonylation reactions has increased considerably. Although
many reviews/chapters/books on carbonylation reactions have been published, summaries …

In the last twenty years, nickel has successfully imprinted its role in the field of homogeneous
catalysis as a valid and complementary alternative to palladium and platinum catalysts …

The synthesis of complex polysubstituted aromatic molecules from simple precursors is a
central goal in organic chemistry. In this study, we developed an approach for the ortho …

A nickel‐catalyzed reductive cross‐electrophile coupling between the redox‐active N‐
trifluoroethoxyphthalimide and iodoarenes is documented. The protocol reproduces a formal …

Novel strategy for acid chlorides formation that do not use carboxylic acids is particularly
attractive in chemical synthesis but remains challenging. Herein, we reported the …

We report the palladium-catalyzed double-decarbonylative synthesis of aryl thioethers by an
aryl exchange reaction between amides and thioesters. In this method, amides serve as aryl …

The dangerous chemical hydrogen fluoride sits at the apex of the fluorochemical industry,
but the substantial hazards linked to its production under harsh conditions (above 300 …

Carbon–carbon (C–C) bonds are ubiquitous but are among the least reactive bonds in
organic chemistry. Recently, catalytic approaches to activate C–C bonds by transition metals …

The application of carboxy‐MIDA‐boronate (MIDA= N‐methyliminodiacetic acid) as an in
situ CO surrogate for various palladium‐catalyzed transformations is described. Carboxy …