Recyclable/degradable materials via the insertion of labile/cleavable bonds using a comonomer approach
C Lefay, Y Guillaneuf - Progress in Polymer Science, 2023 - Elsevier
Polymers have many advantages such as low weight, low cost, and, importantly, stability
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …
under thermal, chemical, and mechanical stress. This stability, on the other hand, leads to …
Stimuli-cleavable moiety enabled vinyl polymer degradation and emerging applications
Vinyl polymers have become ubiquitous products in our modern world, thanks to their
exceptional strength, durability, and resistance to chemicals, all of which result from their …
exceptional strength, durability, and resistance to chemicals, all of which result from their …
Cleavable comonomers for chemically recyclable polystyrene: a general approach to vinyl polymer circularity
Many common polymers, especially vinyl polymers, are inherently difficult to chemically
recycle and are environmentally persistent. The introduction of low levels of cleavable …
recycle and are environmentally persistent. The introduction of low levels of cleavable …
Controlled-Radical Polymerization of α-Lipoic Acid: A General Route to Degradable Vinyl Copolymers
KR Albanese, PT Morris, J Read de Alaniz… - Journal of the …, 2023 - ACS Publications
Here, we present the synthesis and characterization of statistical and block copolymers
containing α-lipoic acid (LA) using reversible addition–fragmentation chain-transfer (RAFT) …
containing α-lipoic acid (LA) using reversible addition–fragmentation chain-transfer (RAFT) …
100th anniversary of macromolecular science viewpoint: Degradable polymers from radical ring-opening polymerization: Latest advances, new directions, and …
Radical ring-opening polymerization (rROP) allows facile incorporation of labile groups (eg,
ester) into the main chain of vinyl polymers to obtain (bio) degradable materials. rROP has …
ester) into the main chain of vinyl polymers to obtain (bio) degradable materials. rROP has …
Building tunable degradation into high-performance poly (acrylate) pressure-sensitive adhesives
KR Albanese, Y Okayama, PT Morris, M Gerst… - ACS Macro …, 2023 - ACS Publications
Pressure-sensitive adhesives (PSAs) based on poly (acrylate) chemistry are common in a
wide variety of applications, but the absence of backbone degradability causes issues with …
wide variety of applications, but the absence of backbone degradability causes issues with …
Radical approach to thioester-containing polymers
A new approach to radical ring-opening polymerization is presented that employs a new
thionolactone monomer to generate polymers with thioester-containing backbones. The use …
thionolactone monomer to generate polymers with thioester-containing backbones. The use …
Degradable vinyl random copolymers via photocontrolled radical ring‐opening cascade copolymerization
Degradable vinyl polymers by radical ring‐opening polymerization are promising solutions
to the challenges caused by non‐degradable vinyl plastics. However, achieving even …
to the challenges caused by non‐degradable vinyl plastics. However, achieving even …
Degradable polystyrene via the cleavable comonomer approach
N Gil, B Caron, D Siri, J Roche, S Hadiouch… - …, 2022 - ACS Publications
Polystyrene (PS) is a major commodity polymer widely used in various applications ranging
from packaging to insulation thanks to its low cost, high stiffness, and transparency as well …
from packaging to insulation thanks to its low cost, high stiffness, and transparency as well …
Polyprodrug antimicrobials: remarkable membrane damage and concurrent drug release to combat antibiotic resistance of methicillin‐resistant staphylococcus aureus
The increased threat of antibiotic resistance has created an urgent need for new strategies.
Herein, polyprodrug antimicrobials are proposed to mimic antimicrobial peptides appended …
Herein, polyprodrug antimicrobials are proposed to mimic antimicrobial peptides appended …