This review summarizes the advancements in rhodium-catalyzed asymmetric C–H
functionalization reactions during the last two decades. Parallel to the rapidly developed …

The creation of new chiral ligands capable of providing high stereocontrol in metal‐
catalyzed reactions is crucial in modern organic synthesis. The production of bioactive …

In recent years, the merging of electrosynthesis with 3d metal catalyzed C− H activation has
emerged as a sustainable and powerful technique in organic synthesis. Despite the …

Direct catalytic transformation of C–H bonds to new functionalities has provided a powerful
strategy to synthesize complex molecular scaffolds in a straightforward way. Unstinting …

An enantioselective C− H arylation of phosphine oxides with o‐quinone diazides catalyzed
by an iridium (III) complex bearing an atropchiral cyclopentadienyl (Cpx) ligand and …

Transition‐metal‐catalyzed C− H functionalization reactions with Cp* MIII catalysts (M= Co,
Rh, Ir) have found a wide variety of applications in organic synthesis. Albeit the intrinsic …

Enantiomeric access to pentatomic biaryls is challenging due to their relatively low rotational
barrier. Reported herein is the mild and highly enantioselective synthesis of 2, 3′-biindolyls …

Enantioselective C–H functionalization is a powerful tool for synthesizing chiral molecules.
In the past few years, the combination of high-valent group 9 metals with achiral Cpx ligands …

Recent advances in CpxMIII catalysis (M= Co, Rh, Ir) have enabled a variety of
enantioselective C (sp2)− H functionalization reactions, but enantioselective C (sp3)− H …

Herein, we disclose an efficient cobalt-catalyzed enantioselective C–H activation and
annulation of benzamides with alkenes. This transformation is facilitated via the …