Data on the electronic structure and redox, magnetic, luminescent, nonlinear optical and
catalytic properties of tri-and tetranuclear molybdenum and tungsten chalcogenide clusters …

Inverse coordination is the formation of metal complexes in which the arrangement of
acceptor and donor sites is opposite to that occurring in conventional coordination …

Functionalized anilines are valuable intermediates for the manufacture of dyes, pigments,
agrochemicals, and pharmaceuticals.[1] Furthermore, they represent key precursors for the …

Azobenzene hydrogenation is catalyzed under moderate conditions by a cuboidal Mo3 (μ3-
S)(μ-S) 3 diamino complex via a cluster catalysis mechanism. Dihydrogen activation by the …

Herein, we report a novel well‐defined diamino Mo3S4‐based catalyst system for the
reduction of nitroarenes and azo compounds to the corresponding anilines with silanes as …

The catalytic hydrodefluorination (HDF) of pentafluoropyridine in the presence of arylsilanes
is catalyzed by the tungsten and molybdenum (IV) cluster hydrides of formula [M3S4H3 …

Formic acid (FA) dehydrogenation is an attractive process in the implementation of a
hydrogen economy. To make this process greener and less costly, the interest nowadays is …

We report the syntheses and characterizations, in the solid state and in solution, of three
new cyclic polyoxothiomolybdates self-assembled around 2, 5-dimethylterephthalate (DMT) …

Formic acid is considered as a promising hydrogen storage material in the context of a
green hydrogen economy. In this work, we present a series of aminophosphino and …

Bifunctional catalysis of frustrated Lewis pairs (FLPs) is one of the most active frontier areas
in catalytic hydrogenation. The first MoIV-γ-Keggin-like cluster H2 [(py3MOIV3) 2MOVI7O32 …