Structure and Dynamics of Zr6O8 Metal–Organic Framework Node Surfaces Probed with Ethanol Dehydration as a Catalytic Test Reaction

D Yang, MA Ortuno, V Bernales… - Journal of the …, 2018 - ACS Publications
Some metal–organic frameworks (MOFs) incorporate nodes that are metal oxide clusters
such as Zr6O8. Vacancies on the node surfaces, accidental or by design, act as catalytic …

Advances in understanding the selective hydrogenolysis of biomass derivatives

YS Yun, CE Berdugo-Díaz, DW Flaherty - ACS Catalysis, 2021 - ACS Publications
Biomass has attracted great attention as an alternative to petrochemicals for the production
of valuable chemicals and fuels. Hydrogenolysis reactions over heterogeneous catalysts …

Disentangling origins of adhesive bonding at interfaces between epoxy/amine adhesive and aluminum

K Akaike, Y Shimoi, T Miura, H Morita, H Akiyama… - Langmuir, 2023 - ACS Publications
Joining metals by adhesive bonding is essential in widespread fields such as mobility,
dentistry, and electronics. Although adhesive technology has grown since the 1920s, the …

Scavenging performance and antioxidant activity of γ-alumina nanoparticles towards DPPH free radical: Spectroscopic and DFT-D studies

M Zamani, AM Delfani, M Jabbari - … Acta Part A: Molecular and Biomolecular …, 2018 - Elsevier
The radical scavenging performance and antioxidant activity of γ-alumina nanoparticles
towards 2, 2-diphenyl-1-picrylhydrazyl (DPPH) free radical were investigated by …

Microkinetic model of propylene oligomerization on Brønsted acidic zeolites at low conversion

S Vernuccio, EE Bickel, R Gounder, LJ Broadbelt - ACS Catalysis, 2019 - ACS Publications
The construction of a computational framework that describes the kinetic details of the
propylene oligomerization reaction network on Brønsted acidic zeolites is particularly …

[HTML][HTML] A perspective on catalytic production of olefinic compounds from biomass

Y Nakagawa, M Yabushita, K Tomishige - RSC Sustainability, 2023 - pubs.rsc.org
Chemical syntheses of industrially important olefins and unsaturated oxygenates from
biomass are reviewed. Their syntheses are discussed in two aspects: common key reactions …

Insights into the mechanism of ethanol conversion into 1, 3-butadiene on Zr-β zeolite

M Zhang, X Guan, J Zhuang, Y Yu - Applied Surface Science, 2022 - Elsevier
butadiene is an important monomer in the production of rubber, resin and engineering
plastics. In recent years, ethanol to 1, 3-butadiene (ETB) has been widely studied. Zr-β …

Application of modulation excitation-phase sensitive detection-DRIFTS for in situ/operando characterization of heterogeneous catalysts

PD Srinivasan, BS Patil, H Zhu… - Reaction Chemistry & …, 2019 - pubs.rsc.org
This work describes the application of in situ/operando modulation excitation-phase
sensitive detection-diffuse reflectance Fourier transform spectroscopy (ME-PSD-DRIFTS) for …

Ligand exchange-mediated activation and stabilization of a Re-based olefin metathesis catalyst by chlorinated alumina

A Gallo, A Fong, KC Szeto, J Rieb… - Journal of the …, 2016 - ACS Publications
Extensive chlorination of γ-Al2O3 results in the formation of highly Lewis acidic surface
domains depleted in surface hydroxyl groups. Adsorption of methyltrioxorhenium (MTO) onto …

Enhanced ethanol dehydration on γ-Al2O3 supported cobalt catalyst

PD Srinivasan, K Khivantsev, JMM Tengco, H Zhu… - Journal of …, 2019 - Elsevier
Ethanol catalytic dehydration was studied on a γ-Al 2 O 3 and Co-Al 2 O 3 catalyst prepared
by the strong electrostatic adsorption (SEA) method. Specific surface area characterization …