Recent advances in organic reactions involving elemental sulfur

TB Nguyen - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
Elemental sulfur has been known since Antiquity and found widespread applications in the
preparation of black gunpowder, the synthesis of sulfuric acid as well as other sulfur …

Recent advances in the field of multicarbene and multimetal carbene complexes of the Fischer-type

DI Bezuidenhout, S Lotz, DC Liles… - Coordination Chemistry …, 2012 - Elsevier
This review article covers the development of Fischer carbene complexes since the year
2000, with specific focus on carbene complexes bearing metal-containing fragments as …

Singlet carbenes derived from ferrocene and closely related sandwich complexes

U Siemeling - European Journal of Inorganic Chemistry, 2012 - Wiley Online Library
This microreview describes the tremendous progress that has been made during the past
decade in the area of ferrocene‐based singlet carbenes, the vast majority of which belong to …

Base-Catalyzed Transesterification of Thionoesters

JJ Newton, R Britton, CM Friesen - The Journal of Organic …, 2018 - ACS Publications
Here we report a convenient synthesis of thionoesters by base-catalyzed transesterification.
Benzyl and alkyl thionobenzoates and thionoheterobenzoates were efficiently prepared …

Ferrocenylselenoamides: synthesis, characterization and cytotoxic properties

AI Gutiérrez-Hernández, JG López-Cortés… - Journal of Medicinal …, 2012 - ACS Publications
A new series of ferrocenyl selenoamides 7–11 (FcSeNH (CH2) n CH2 (R) OH, n= 1, 2, 3, R=
H, Me, Ph) were prepared in good yields by selenative demetalation of Fischer …

Chiral bidentate [N, S]-ferrocene ligands based on a thiazoline framework. Synthesis and use in palladium-catalyzed asymmetric allylic alkylation

EP Sánchez-Rodríguez, F Hochberger-Roa… - Dalton …, 2017 - pubs.rsc.org
An efficient method to obtain chiral 1, 2-disubstituted ferrocenyl ligands has been
developed. The introduction of planar chirality was accomplished by using 2-thiazoline as …

Impact of O→ S exchange in ferrocenyl amides on the structure and redox chemistry

T Kienz, C Förster, K Heinze - Organometallics, 2014 - ACS Publications
The conformations and redox chemistry of ferrocenyl amides have been investigated in
considerable depth in the last few years, while ferrocenyl thioamides have attracted less …

Infrared irradiation or microwave assisted cross-coupling reactions using sulfur-containing ferrocenyl-palladacycles

JA Balam-Villarreal, CI Sandoval-Chávez… - Journal of …, 2016 - Elsevier
The synthesis of four new sulfur-containing palladacycles 3a-d [FcC (S) OEtPdClZR 3,
where: 3a, ZR 3: PPh 3; 3b, ZR 3: P (o-Tol) 3; 3c, ZR 3: PMe 3; 3d, ZR 3: SbPh 3] from …

Mo fischer carbene complexes: a DFT study on the prediction of redox potentials

AA Adeniyi, M Landman… - Journal of The …, 2021 - iopscience.iop.org
The electronic properties of Fischer carbenes [Mo (CO) 5− n (L n){C (Y) Ar}](n= 1–2, Ar= aryl
group) can be tuned by changing the metal environment and their carbene substituents. The …

2-Ferrocenyl-2-thiazoline as a building block of novel phosphine-free ligands

R Corona-Sánchez, RA Toscano… - Dalton …, 2013 - pubs.rsc.org
New 1, 2-disubstituted ferrocenes [5 (b–j), in which R=–SMe,–SPh,–SiPr,–SiMe3,–SePh,–
SnBu3,–B (OH) 2,–Me,–I] with a thiazoline ring in the ferrocene backbone using as key …