Molecular main group metal hydrides
This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …
Group 14 inorganic hydrocarbon analogues
E Rivard - Chemical Society Reviews, 2016 - pubs.rsc.org
Hydrocarbons are ubiquitous in our daily lives due to their use as commodity materials (eg
polyethylene) and fuels. Heavier Group 14 element hydrides, termed herein as “inorganic …
polyethylene) and fuels. Heavier Group 14 element hydrides, termed herein as “inorganic …
Donor–acceptor chemistry in the main group
E Rivard - Dalton Transactions, 2014 - pubs.rsc.org
This Perspective article summarizes recent progress from our laboratory in the isolation of
reactive main group species using a general donor–acceptor protocol. A highlight of this …
reactive main group species using a general donor–acceptor protocol. A highlight of this …
Metal‐Free Addition/Head‐to‐Tail Polymerization of Transient Phosphinoboranes, RPH‐BH2: A Route to Poly(alkylphosphinoboranes)
C Marquardt, T Jurca, KC Schwan… - Angewandte Chemie …, 2015 - Wiley Online Library
Mild thermolysis of Lewis base stabilized phosphinoborane monomers R1R2P BH2⋅
NMe3 (R1, R2= H, Ph, or tBu/H) at room temperature to 100° C provides a convenient new …
NMe3 (R1, R2= H, Ph, or tBu/H) at room temperature to 100° C provides a convenient new …
Synthesis and Application of Alkali Metal Antimonide—A New Approach to Antimony Chemistry
K Dollberg, S Schneider, RM Richter… - Angewandte Chemie …, 2022 - Wiley Online Library
Alkali metal dihydrogen‐antimonides [M (L) xSbH2], short: alkali metal antimonides (M= Li,
Na, K, Rb, Cs; 1: L= pmdta; 2: L= crown‐ether), were prepared from stibine and n …
Na, K, Rb, Cs; 1: L= pmdta; 2: L= crown‐ether), were prepared from stibine and n …
Synthesis of bismuthanyl-substituted monomeric triel hydrides
R Szlosek, C Marquardt, O Hegen, G Balázs… - Chemical …, 2024 - pubs.rsc.org
The syntheses and characterizations of the first bismuthanylborane monomers stabilized
only by a donor in D· BH2Bi (SiMe3) 2 (D= DMAP 1a, IDipp 1b, IMe41c; DMAP= 4 …
only by a donor in D· BH2Bi (SiMe3) 2 (D= DMAP 1a, IDipp 1b, IMe41c; DMAP= 4 …
Phosphanylalanes and Phosphanylgallanes Stabilized only by a Lewis Base
MAK Weinhart, AS Lisovenko… - Angewandte Chemie …, 2020 - Wiley Online Library
The synthesis and characterization of the first parent phosphanylalane and
phosphanylgallane stabilized only by a Lewis base (LB) are reported. The corresponding …
phosphanylgallane stabilized only by a Lewis base (LB) are reported. The corresponding …
Iridium-catalysed dehydrocoupling of aryl phosphine–borane adducts: synthesis and characterisation of high molecular weight poly (phosphinoboranes)
USD Paul, H Braunschweig, U Radius - Chemical Communications, 2016 - pubs.rsc.org
The thermal dehydrogenative coupling of aryl phosphine–borane adducts with iridium
complexes bearing a bis (phosphinite) pincer ligand is reported. This catalysis produces …
complexes bearing a bis (phosphinite) pincer ligand is reported. This catalysis produces …
NHC‐Stabilized Mixed Group 13/14/15 Element Hydrides
MT Ackermann, R Szlosek, C Riesinger… - … A European Journal, 2024 - Wiley Online Library
The syntheses of novel N‐heterocyclic carbene (NHC) adducts of group 13, 14 and 15
element hydrides are reported. Salt metathesis reactions between NaPH2 and IDipp⋅ …
element hydrides are reported. Salt metathesis reactions between NaPH2 and IDipp⋅ …
Isolation and characterization of lewis base stabilized monomeric parent stibanylboranes
C Marquardt, O Hegen, M Hautmann… - Angewandte Chemie …, 2015 - Wiley Online Library
The synthesis of the Lewis base stabilized monomeric parent compound of
stibanylboranes,“H2Sb BH2”, is reported. Through a salt metathesis route, the silyl …
stibanylboranes,“H2Sb BH2”, is reported. Through a salt metathesis route, the silyl …