Zeolite membranes: microstructure characterization and permeation mechanisms
Since their first synthesis in the 1940s, zeolites have found wide applications in catalysis, ion-
exchange, and adsorption. Although the uniform, molecular-size pores of zeolites and their …
exchange, and adsorption. Although the uniform, molecular-size pores of zeolites and their …
A review of adsorbate and temperature-induced zeolite framework flexibility
B Ilić, SG Wettstein - Microporous and Mesoporous Materials, 2017 - Elsevier
It has been known for over 50 years that zeolite frameworks are flexible, yet, until recently,
this characteristic has not been exploited. Framework flexibility can have significant …
this characteristic has not been exploited. Framework flexibility can have significant …
Separation of acetone, butanol and ethanol (ABE) from dilute aqueous solutions by silicalite-1/PDMS hybrid pervaporation membranes
To study the effects of different factors on the separation of acetone, butanol, and ethanol
(ABE) from ABE–water solutions by pervaporation with silicalite-1/polydimethylsiloxane …
(ABE) from ABE–water solutions by pervaporation with silicalite-1/polydimethylsiloxane …
Hydrogen bonding effects in adsorption of water− alcohol mixtures in zeolites and the consequences for the characteristics of the Maxwell− Stefan diffusivities
R Krishna, JM van Baten - Langmuir, 2010 - ACS Publications
This work highlights a variety of peculiar characteristics of adsorption and diffusion of polar
molecules such as water, methanol and ethanol in zeolites. These peculiarities are …
molecules such as water, methanol and ethanol in zeolites. These peculiarities are …
Modification of silicalite-1 by vinyltrimethoxysilane (VTMS) and preparation of silicalite-1 filled polydimethylsiloxane (PDMS) hybrid pervaporation membranes
In preparation of inorganic particles filled polymer membranes, coupling agents can help to
improve the compatibility between inorganic filler and polymer matrix. In this paper, surface …
improve the compatibility between inorganic filler and polymer matrix. In this paper, surface …
Differences in Al distribution and acidic properties between RTH-type zeolites synthesized with OSDAs and without OSDAs
M Liu, T Yokoi, M Yoshioka, H Imai, JN Kondo… - Physical Chemistry …, 2014 - pubs.rsc.org
In addition to the original preparation route of the RTH-type zeolites using 1, 2, 2, 6, 6-
pentamethylpiperidine (PMP) as an organic structure directing agent (OSDA), we have …
pentamethylpiperidine (PMP) as an organic structure directing agent (OSDA), we have …
Understanding butanol recovery and coupling effects in pervaporation of Acetone-Butanol-Ethanol (ABE) solutions: A modelling and experimental study
The sustainable downstream recovery of bio-butanol from multicomponent fermentation
broths through organophilic pervaporation is still challenged, in part, by a limited knowledge …
broths through organophilic pervaporation is still challenged, in part, by a limited knowledge …
Improved performance of PDMS/silicalite-1 pervaporation membranes via designing new silicalite-1 particles
X Zhuang, X Chen, Y Su, W Cao, Y Wan - Journal of Membrane Science, 2015 - Elsevier
In order to improve the separation performance of pervaporation (PV) membranes, different
silicalite-1 particles were prepared by hydrothermal synthesis in fluoride (F) or alkaline (OH) …
silicalite-1 particles were prepared by hydrothermal synthesis in fluoride (F) or alkaline (OH) …
Influence of zeolite crystal expansion/contraction on NaA zeolite membrane separations
SG Sorenson, EA Payzant, WT Gibbons… - Journal of Membrane …, 2011 - Elsevier
In situ powder XRD measurements showed that adsorption causes the NaA zeolite unit cell
to contract or expand, and these changes depend on adsorbate loading. Changes in zeolite …
to contract or expand, and these changes depend on adsorbate loading. Changes in zeolite …
Fluorine doping of microporous organosilica membranes for pore size control and enhanced hydrophobic properties
M Kanezashi, M Murata, H Nagasawa, T Tsuru - ACS omega, 2018 - ACS Publications
Fluorine-doped organosilica membranes for gas and pervaporation (PV) separation were
fabricated using a sol–gel method. NH4F and bis (triethoxysilyl) methane (BTESM) were …
fabricated using a sol–gel method. NH4F and bis (triethoxysilyl) methane (BTESM) were …